大学化学 >> 2025, Vol. 40 >> Issue (10): 263-275.doi: 10.12461/PKU.DXHX202412021

化学实验 上一篇    下一篇

综合化学实验设计：非稠环电子受体的设计、合成及光电性质研究

刘文旭1,3, 韩峰1, 王博轩1,3, 刘骅驿3, 古晓斌2, 张昕2, 刘瑶3   

  1. 1 北京化工大学化学学院有机化学系, 北京 100029;
    2 中国科学院大学材料科学与光电技术学院, 材料与光电研究中心, 北京 101408;
    3 北京化工大学软物质科学与工程高精尖创新中心, 北京 100029
  • 收稿日期:2024-12-02 录用日期:2025-04-07 发布日期:2025-09-17
  • 通讯作者: 张昕, 刘瑶 E-mail:zhangxin2019@ucas.ac.cn;liuyao@mail.buct.edu.cn
  • 基金资助:
    中国科学院青年创新促进会(2022165);北京化工大学化学学院 2024 年本科教育教学改革研究项目(2024HXJG28)

Comprehensive Chemical Experiment: Design, Synthesis, and Photoelectronic Properties Study of Fully Non-Fused Ring Electron Acceptors

Wenxu Liu1,3, Feng Han1, Boxuan Wang1,3, Huayi Liu3, Xiaobin Gu2, Xin Zhang2, Yao Liu3   

  1. 1 Department of Organic Chemistry, College of Chemistry, Beijing University of Chemical Technology, Beijing 100029, China;
    2 Center of Materials Science and Optoelectronics Engineering, College of Materials Science and Opto-Electronic Technology, University of Chinese Academy of Sciences, Beijing 101408, China;
    3 Beijing Advanced Innovation Center for Soft Matter Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China
  • Received:2024-12-02 Accepted:2025-04-07 Published:2025-09-17
  • Contact: Xin Zhang, Yao Liu E-mail:zhangxin2019@ucas.ac.cn;liuyao@mail.buct.edu.cn

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摘要： 本文设计了一个以非稠环电子受体材料为核心的综合实验，涵盖分子合成及光电性质研究。实验创新性地将太阳能利用与Suzuki偶联反应引入教学，通过“文献研读-实验操作-机理探讨”模式深化“结构决定性质”的化学思维。培养学生实验操作及数据处理能力，同时融入绿色化学理念，有效提升学生的创新意识与协作能力，为科研深造奠定基础。

关键词: 综合化学实验, 电子受体, 光电性质, 绿色化学观

Abstract: This study presents a comprehensive experiment focusing on the design and synthesis of non-fused ring electron acceptors, along with the investigation of their photoelectronic properties. The experiment innovatively incorporates solar energy utilization and Suzuki coupling reactions into the curriculum, employing a “literature review-experimental manipulation-mechanistic exploration” approach to reinforce the fundamental chemical principle that “structure determines properties”. This methodology aims to enhance students’ experimental skills and data processing capabilities, while integrating principles of green chemistry. The approach effectively fosters students’ innovative thinking and collaborative skills, thereby providing a robust foundation for future scientific research.

Key words: Comprehensive chemical experiment, Electron acceptor, Photoelectronic property, Green chemistry concept