新工科背景下二维共轭金属-有机框架在能源储存中的研究进展

doi:10.12461/PKU.DXHX202607011

摘要/Abstract

摘要： 随着我国“双碳”战略的深入实施，开发高效、安全、可持续的二次电池储能技术已成为“新工科”背景下化学与材料学科的研究热点。二维共轭金属-有机框架(2D c-MOFs)作为一类新兴的二维共轭配位高分子，因其独特的π共轭结构、可调控的组成与高度有序的晶体结构，在能源储存领域展现出广阔应用前景。本文旨在介绍2D c-MOFs的结构设计策略，重点阐述其在锂/钠/钾离子电池及水系锌离子电池中的应用现状与储能机制。同时，结合“新工科”背景，探讨该前沿方向在高分子化学教学中的融入路径与实践意义，以期为培养具有跨学科视野的新型工程人才提供有益参考。

关键词: 新工科, 二维共轭金属-有机框架, 二次电池, 储能机制

Abstract: With the ongoing implementation of China’s “dual-carbon” strategy, the development of efficient, safe, and sustainable rechargeable battery technologies has become a central research priority in chemistry and materials science within the context of Emerging Engineering Education. Two-dimensional conjugated metal– organic frameworks (2D c-MOFs), as an emerging class of two-dimensional conjugated coordination polymers, hold great promise for energy storage applications owing to their unique π-conjugated architecture, tunable compositions, and highly ordered crystalline structures. This article outlines the structural design strategies for 2D c-MOFs and highlights their current applications in lithium-ion, sodium-ion, potassium-ion, and aqueous zinc-ion batteries, with particular emphasis on the underlying energy storage mechanisms. Furthermore, in light of Emerging Engineering Education, this review explores the integration of this cutting-edge topic into polymer chemistry teaching and discusses its practical implications, aiming to offer valuable insights for nurturing interdisciplinary engineering talents.

Key words: Emerging Engineering Education, Two-dimensional conjugated metal-organic frameworks, Rechargeable batteries, Energy storage mechanisms

何欣泽, 苏熹, 陈龙. 新工科背景下二维共轭金属-有机框架在能源储存中的研究进展[J]. 大学化学, 2026, (): 2607011.

Xinze He, Xi Su, Long Chen. Advances in two-dimensional conjugated metal–organic frameworks for energy storage under Emerging Engineering Education[J]. University Chemistry, 2026, (): 2607011.

链接本文: https://www.dxhx.pku.edu.cn/CN/10.12461/PKU.DXHX202607011

https://www.dxhx.pku.edu.cn/CN/Y2026/V/I/2607011

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