大学化学 >> 2026, Vol. 41 >> Issue (8): 321-330.doi: 10.12461/PKU.DXHX202507123

化学实验 上一篇    下一篇

电解水制氢耦合5-羟甲基糠醛氧化制2,5-呋喃二甲酸创新实验设计

周华, 李雨晴, 张睿, 钱佳龙, 栗振华, 邵明飞   

  1. 北京化工大学化学学院, 北京 100029
  • 收稿日期:2025-07-28 录用日期:2025-08-15 发布日期:2026-08-25
  • 通讯作者: 邵明飞 E-mail:shaomf@mail.buct.edu.cn Mingfei Shao
  • 基金资助:
    北京化工大学本科教育教学改革研究项目(2024HXJG24,2025HXJG17)

Innovative experiment on electrocatalytic hydrogen production coupled with 5-hydroxymethylfurfural oxidation to 2,5-furandicarboxylic acid

Hua Zhou, Yuqing Li, Rui Zhang, Jialong Qian, Zhenhua Li, Mingfei Shao   

  1. College of Chemistry, Beijing University of Chemical Technology, Beijing 100029, China
  • Received:2025-07-28 Accepted:2025-08-15 Published:2026-08-25
  • Contact: Mingfei Shao E-mail:shaomf@mail.buct.edu.cn

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摘要： 电化学是重要的基础和应用科学，然而大学化学实验课程中缺少相应的实验教学。在此，我们设计了一个8学时的电化学实验。利用电解水制氢过程中阳极5-羟甲基糠醛氧化替代传统的析氧反应，生成高附加值的2,5-呋喃二甲酸，降低产氢的电耗。本实验有助于加深学生对理论知识的理解，了解前沿研究，激发科研兴趣。

关键词: 化学实验, 电合成, 电氧化, 生物质转化

Abstract: Electrochemistry serves as a crucial discipline in both fundamental and applied sciences. However, most university chemistry laboratory curricula lack corresponding experimental modules in this field. To address this gap, we designed an eight-hour electrochemical experiment. By replacing the conventional oxygen evolution reaction with the oxidation of 5-hydroxymethylfurfural, we successfully produced high-value-added 2,5-furandicarboxylic acid while simultaneously reducing the energy consumption of hydrogen production. This experiment enables students to deepen their understanding of electrochemical principles, gain insights into cutting-edge research developments in chemistry, and cultivate their interest in scientific inquiry.

Key words: Chemistry experiment, Electrosynthesis, Electrooxidation, Biomass conversion