大学化学 >> 2026, Vol. 41 >> Issue (5): 149-158.doi: 10.12461/PKU.DXHX202511095

所属专题: 第5届全国大学生化学实验创新设计大赛

专题 上一篇    

“神笔马良”——基于热致变色染料的创意绘画科普演示实验

刘全, 冯健, 屈岳坤, 白佳瑶, 任旭年, 王琦, 徐海涛, 张晟瑞   

  1. 陕西理工大学化学与环境科学学院, 陕西 汉中 723000
  • 收稿日期:2025-11-14 录用日期:2026-02-25 发布日期:2026-05-21
  • 通讯作者: 刘全 E-mail:liuq@snut.edu.cn Quan Liu
  • 基金资助:
    陕西高校青年创新团队(2022.94);陕西理工大学研究生教育教学改革研究项目(SLGYJG2501)

“Ma Liang and his magic brush”: a science demonstration of creative painting using thermochromic pigments

Quan Liu, Jian Feng, Yuekun Qu, Jiayao Bai, Xunian Ren, Qi Wang, Haitao Xu, Shengrui Zhang   

  1. College of Chemical & Environment Science, Shaanxi University of Technology, Hanzhong 723000, Shaanxi Province, China
  • Received:2025-11-14 Accepted:2026-02-25 Published:2026-05-21
  • Contact: Quan Liu E-mail:liuq@snut.edu.cn

摘要: 荧烷染料作为氧杂蒽类染料的重要分支,是一类重要的杂环化合物,其结构具有受外部刺激发生显著变化这一特性,导致其颜色随之改变。荧烷染料优异的光物理性质使其作为生物活性结构、染料或荧光试剂在生物成像中具有相当大的应用。本科普实验以荧烷染料为功能基元,制备荧烷染料微胶囊。尝试将荧烷染料微胶囊配制成油墨,通过油画、水粉画方式演示热致变色现象。进一步,为便于幼儿园和小学低年级儿童体验,对现有染料油墨进行器材化改进,设计了装有油墨的变色画笔。画笔体积小巧质量轻,可随身携带,所有原料器材方便易得,可极大减少实验准备的工作量。通过实验互动与演示讲解让观众们感受到科学变化的神奇,激发观众对化学学科的浓厚兴趣。

关键词: 萤烷, 染料, 温致变色, 微胶囊, 演示实验

Abstract: As an important subclass of xanthene dyes, fluorane dyes represent a significant group of heterocyclic compounds. Their molecular structure exhibits remarkable responsiveness to external stimuli, leading to distinct color changes. Owing to their excellent photophysical properties, fluorane dyes find substantial applications in biological imaging as bioactive structures, dyes, or fluorescent reagents. This science popularization experiment employs fluorane dye as the functional component to prepare microencapsulated fluorane dyes. The prepared dye microcapsules were formulated into inks to demonstrate thermochromic phenomena through oil and gouache painting techniques. To enhance accessibility for kindergarten and elementary school children, we further developed the dye ink into an instrumented form by designing an ink-filled thermochromic brush. The brush features compact size, lightweight construction, and portability, while all required materials are readily available, significantly reducing experimental preparation efforts. Through interactive demonstrations, this experiment allows participants to witness the marvels of scientific transformations, thereby fostering their interest in chemistry.

Key words: Fluorane, Dye, Thermochromic, Microcapsules, Demonstration experiment