大学化学

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CO2时代的“捕手”:MOFs的高效捕集与转化之道

张鹛媚, 王璐, 陈世贵   

  1. 武汉大学高等研究院, 湖北 武汉 430072
  • 收稿日期:2026-04-07 录用日期:2026-06-29
  • 通讯作者: 陈世贵, 王璐 E-mail:sgchen@whu.edu.cn;wanglu-027@whu.edu.cn Shigui Chen, Lu Wang
  • 基金资助:
    国家自然科学基金(22371218,21702153,52270070,21801194)

The “catcher” in the CO2 era: efficient capture and conversion of MOFs

Meimei Zhang, Lu Wang, Shigui Chen   

  1. The Institute for Advanced Studies, Wuhan University, Wuhan 430072, Hubei Province, China
  • Received:2026-04-07 Accepted:2026-06-29
  • Contact: Shigui Chen, Lu Wang E-mail:sgchen@whu.edu.cn;wanglu-027@whu.edu.cn

摘要: 随着全球CO2排放量持续攀升,开发高效碳捕集与转化技术已成为实现“碳中和”目标的关键。金属有机框架材料(Metal-Organic Frameworks,MOFs)因其超高比表面积(可达7000 m2·g-1以上)、可精确调控的孔道结构及化学组成多样性,被视为新一代CO2捕集材料的理想候选。本文系统介绍了针对实际CO2捕集工况下MOFs材料的合成工艺和转化利用技术,并分析了未来工业化应用面对的挑战。本文以简单通俗的语言展开介绍,涵盖广泛受众,以期让公众体会到新材料之美。

关键词: 金属有机框架, CO2捕集, 功能化改性, 原位催化转化, 工业化

Abstract: With global CO2 emissions continuing to escalate, the development of efficient carbon capture and conversion technologies has become essential to achieving the goal of “carbon neutrality”. Metalorganic Frameworks (MOFs) are widely recognized as promising candidates for next-generation CO2 capture materials, owing to their exceptionally high specific surface areas (exceeding 7000 m2·g-1), finely tunable pore architectures, and diverse chemical compositions. This article provides a systematic overview of the synthesis strategies and conversion technologies for MOF materials under realistic CO2 capture conditions, while also examining the challenges that lie ahead for their industrial deployment. Written in an accessible and engaging style, this work aims to popularize the science of MOF-based CO2 capture for a broad readership, fostering a deeper public appreciation of the elegance and potential of advanced materials.

Key words: Metal-organic framework, CO2 capture, Functional modification, In situ catalytic conversion, Industrialization