从基元反应分析过渡金属催化的有机反应

doi:10.12461/PKU.DXHX202604009

大学化学

从基元反应分析过渡金属催化的有机反应

武郭艺潇¹, 顾友昊¹, 张勇健¹, 张延东^1,2

1 厦门大学化学化工学院, 福建厦门 361005;
2 新疆大学化学学院, 新疆乌鲁木齐 830017

收稿日期:2026-04-07 录用日期:2026-07-22
通讯作者: 张延东 E-mail:ydzhang@xmu.edu.cn Yandong Zhang
基金资助:
国家基础科学人才培养基金项目(J1310024)

Analysis of transition metal-catalyzed organic reactions based on elementary reactions

Guoyixiao Wu¹, Youhao Gu¹, Yongjian Zhang¹, Yandong Zhang^1,2

1 College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, China;
2 College of Chemistry, Xinjiang University, Urumqi 830017, Xinjiang Uygur Autonomous Region, China

Received:2026-04-07 Accepted:2026-07-22
Contact: Yandong Zhang E-mail:ydzhang@xmu.edu.cn

摘要/Abstract

摘要： 过渡金属催化的有机反应在工业催化与天然产物合成中应用广泛。尽管其研究历史较长，但在有机化学领域，过渡金属催化仍展现出无限可能，不断延伸并拓展出多样化的研究方向。因此，建立扎实的过渡金属催化理论基础，对于本科生学习该领域的前沿进展具有重要意义。本文首先介绍了过渡金属催化中基元反应的类型、机理与性质，继而通过经典的命名反应实例，对基元反应的组合方式形成全面而系统的认识。本文旨在从基础有机化学的角度，系统梳理过渡金属催化的相关知识，深化化学专业本科生对反应机理、反应性质及经典案例的理解，为学生理解和学习过渡金属催化的前沿进展提供理论支撑。

关键词: 过渡金属催化, 基元反应, 催化循环, 本科有机化学

Abstract: Transition metal-catalyzed organic reactions are widely employed in industrial catalysis and natural product synthesis. Despite their long-standing research history, transition metal catalysis continues to reveal immense potential within organic chemistry, giving rise to diverse and ever-expanding research directions. Consequently, establishing a solid theoretical foundation in transition metal catalysis is essential for undergraduate students to engage with cutting-edge developments in this field. This article begins by introducing the types, mechanisms, and characteristics of elementary reactions involved in transition metal catalysis, followed by a systematic examination of how these elementary steps are integrated, illustrated through classic named reactions. The overarching goal is to provide a coherent overview of transition metal catalysis from the perspective of fundamental organic chemistry, thereby deepening chemistry undergraduates’ understanding of reaction mechanisms, reaction behavior, and representative case studies, and offering theoretical support for their comprehension and exploration of frontier advances in this area.

Key words: Transition metal catalysis, Elementary reaction, Catalytic cycle, Undergraduate organic chemistry

武郭艺潇, 顾友昊, 张勇健, 张延东. 从基元反应分析过渡金属催化的有机反应[J]. 大学化学, 2026, (): 2604009.

Guoyixiao Wu, Youhao Gu, Yongjian Zhang, Yandong Zhang. Analysis of transition metal-catalyzed organic reactions based on elementary reactions[J]. University Chemistry, 2026, (): 2604009.

链接本文: https://www.dxhx.pku.edu.cn/CN/10.12461/PKU.DXHX202604009

https://www.dxhx.pku.edu.cn/CN/Y2026/V/I/2604009

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