大学化学

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光氧化还原-过渡金属协同催化的有机反应

郑治, 沈徐乐, 张均悦, 顾诗雨, 谢兰贵, 苏志   

  1. 南京师范大学化学与材料科学学院, 江苏 南京 210023
  • 收稿日期:2026-04-07 录用日期:2026-06-25
  • 通讯作者: 谢兰贵, 苏志 E-mail:xielg@njnu.edu.cn;zhisu@njnu.edu.cn Langui Xie, Zhi Su

Photoredox-transition metal synergistic catalysis for organic reactions

Zhi Zheng, Xule Shen, Junyue Zhang, Shiyu Gu, Langui Xie, Zhi Su   

  1. School of Chemistry and Materials Science, Nanjing Normal University, Nanjing 210023, Jiangsu Province, China
  • Received:2026-04-07 Accepted:2026-06-25
  • Contact: Langui Xie, Zhi Su E-mail:xielg@njnu.edu.cn;zhisu@njnu.edu.cn

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摘要： 光氧化还原-过渡金属协同催化结合了可见光诱导的温和电子转移过程与过渡金属催化的成键多样性，为有机合成开辟了新的路径。本文围绕这一协同催化策略，系统介绍了其在碳-碳、碳-氮、碳-氧、碳-硫键构建以及多组分反应中的应用实例，并重点讨论了各类反应的具体机制。

关键词: 光氧化还原催化, 过渡金属催化, 协同催化, 交叉偶联

Abstract: The synergistic combination of photoredox catalysis and transition-metal catalysis merges the mild electron-transfer processes enabled by visible light with the bond-forming versatility of transition metals, thereby opening new avenues in organic synthesis. This review focuses on this synergistic catalytic strategy, systematically presenting its applications in the construction of carbon-carbon, carbon-nitrogen, carbon-oxygen, and carbon-sulfur bonds, as well as in multicomponent reactions, with an emphasis on the detailed mechanisms of various reactions.

Key words: Photoredox catalysis, Transition-metal catalysis, Synergistic catalysis, Cross-coupling