大学化学

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无机化学设计实验——离子马达效应及无泵液流电池

赵建军, 潘军青, 刘佳, 蔡梦凡, 罗彬文   

  1. 北京化工大学化学学院, 北京 100029
  • 收稿日期:2026-05-20 录用日期:2026-06-17
  • 通讯作者: 潘军青 E-mail:jqpan@buct.edu.cn Junqing Pan
  • 基金资助:
    北京化工大学本科教育教学改革研究项目(2023075);国家十四五重点研发专项(2023YFC3903500)

Inorganic chemistry design experiment: ion motor effect and pump-free flow batteries

Jianjun Zhao, Junqing Pan, Jia Liu, Mengfan Cai, Binwen Luo   

  1. College of Chemistry, Beijing University of Chemical Technology, Beijing 100029, China
  • Received:2026-05-20 Accepted:2026-06-17
  • Contact: Junqing Pan E-mail:jqpan@buct.edu.cn

摘要: 将科研成果植入化学综合实验,通过利用液流电池充放电过程中离子在洛伦兹力定向驱动下转化为“离子马达”驱动下电解液自适应定向运动来构建无机械泵或外力搅拌的自驱动一体化无泵液流电池。本实验相较于传统无机化学实验具有三大教学创新特色:一是将抽象的洛伦兹力原理通过电解液定向流动予以直观可视化;二是以“无泵”设计逆向启发学生对能量转换与物质传输的深度思考;三是融合无机化学、物理化学、分析化学、力学等多学科知识,体现综合设计理念。实验设计紧扣电化学储能热点,基础理论与前沿科技相结合,通过有趣直观的化学现象激发学生主动探究热情,显著提升了对浓差极化、锌枝晶抑制等核心概念的理解深度和综合实验能力;引导学生探索化学现象背后的机理,增强学生综合运用多学科知识分析和解决问题的能力,提升学生的创新思维能力和综合素质。

关键词: 化学综合实验, 离子马达, 无泵液流电池, 锌离子电池, 锌枝晶

Abstract: In this paper, a comprehensive chemical experiment is reported by integrating research achievements into the curriculum. A self-driven, integrated pump-free flow battery is constructed without mechanical pumps or external stirring, utilizing the directional driving of ions by the Lorentz force during the charging and discharging processes, which enables the electrolyte to achieve adaptive directional movement driven by the “ion motor”. Compared with traditional inorganic chemistry experiments, this design features three major pedagogical innovations: first, the abstract principle of the Lorentz force is visualized through the directional flow of the electrolyte; second, the “pump-free” design inspires students to think deeply about energy conversion and mass transfer in a reverse-engineering manner; third, it integrates multidisciplinary knowledge including inorganic chemistry, physical chemistry, analytical chemistry, and mechanics, embodying a comprehensive design concept. The experimental design closely follows the hotspot of electrochemical energy storage, combining basic theory with cutting-edge science and technology. Through interesting and intuitive chemical phenomena, it stimulates students’ active learning enthusiasm, significantly enhancing their understanding of core concepts such as concentration polarization and zinc dendrite suppression, as well as their comprehensive experimental abilities. It guides students to explore the mechanisms behind chemical phenomena, strengthens their ability to analyze and solve problems by comprehensively applying multidisciplinary knowledge, and improves their innovative thinking ability and overall quality.

Key words: Chemical comprehensive experiment, Ion motor, Pump-free flow battery, Zn-ion battery, Zinc dendrite