大学化学

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氢键有机框架——新型分子基晶态多孔材料

狄正义1,3, 邹水香1, 纪震宇1, 吴明燕1,2   

  1. 1 中国科学院福建物质结构研究所, 福建 福州 350002;
    2 黑龙江大学化学化工与材料学院, 黑龙江 哈尔滨 150080;
    3 天津师范大学化学学院, 天津 300387
  • 收稿日期:2026-01-10 录用日期:2026-02-06
  • 通讯作者: 吴明燕 E-mail:wumy@fjirsm.ac.cn Mingyan Wu
  • 基金资助:
    国家自然科学基金(22271282, 22571295, 22571230)

Hydrogen-bonded organic frameworks: novel molecule-based crystalline porous materials

Zhengyi Di1,3, Shuixiang Zou1, Zhenyu Ji1, Mingyan Wu1,2   

  1. 1 Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, Fujian Province, China;
    2 School of Chemistry and Material Science, Heilongjiang University, Harbin 150080, Heilongjiang Province, China;
    3 College of Chemistry, Tianjin Normal University, Tianjin 300387, China
  • Received:2026-01-10 Accepted:2026-02-06
  • Contact: Mingyan Wu E-mail:wumy@fjirsm.ac.cn

摘要: 氢键有机框架(HOFs)凭借其合成条件温和、结构可设计性强以及良好的生物相容性等独特优势已成为多孔材料领域的研究热点。本文首先阐述了HOFs材料的发展概况;其次,详细介绍了HOFs材料的合成方法;总结了近年来HOFs材料在气体吸附与分离、荧光传感、药物递送及水处理等领域的应用研究成果。最后,探讨了HOFs未来可能的发展方向。

关键词: 晶态材料, 稳定性, 自组装, 应用研究, 设计合成

Abstract: Hydrogen-bonded organic frameworks (HOFs) exhibit distinctive advantages such as mild synthesis conditions, remarkable structural designability, and superior environmental compatibility. These merits have established HOFs as prominent research focus in the field of porous materials. This review first outlines the developmental trajectory of HOFs, followed by a detailed discussion of their primary synthesis methodologies. Furthermore, it comprehensively summarizes recent advancements in HOF materials research, encompassing applications in gas adsorption and separation, fluorescence sensing, drug delivery, and water treatment. Finally, prospective research directions for HOF materials are proposed.

Key words: Crystalline material, Stability, Self-assembly, Application research, Design and synthesis