大学化学

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基于分子间作用力的化工热力学核心概念教学改革与实践——以“逸度”教学单元为例

元辛   

  1. 中山大学化学工程与技术学院, 广东 珠海 519082
  • 收稿日期:2026-04-07 录用日期:2026-04-22
  • 通讯作者: 元辛 E-mail:yuanx29@mail.sysu.edu.cn Xin Yuan
  • 基金资助:
    中山大学2026年校级教学质量与教学改革工程项目

Teaching reform and practice of core concepts in chemical engineering thermodynamics based on intermolecular forces: taking the “fugacity” teaching unit as an example

Xin Yuan   

  1. School of Chemical Engineering and Technology, Sun Yat-sen University, Zhuhai 519082, Guangdong Province, China
  • Received:2026-04-07 Accepted:2026-04-22
  • Contact: Xin Yuan E-mail:yuanx29@mail.sysu.edu.cn

摘要: 针对化工热力学核心概念“逸度”教学中普遍存在的概念抽象、理解割裂、应用脱节的痛点,本文提出了一种以分子间引力-斥力动态博弈为核心锚点的递进式教学改革方案。该方案打破了传统定义-推导-刷题的线性教学模式,重构了微观分子本质-宏观热力学现象-数学定量表达-工程实际应用的认知闭环,设计了系列可视化教学图例,将抽象的热力学概念与学生已有的分子物理知识深度融合。教学实践结果表明,该改革方案使学生对逸度概念的本质理解正确率从38.2%提升至92.7%,同时明显增强了学生的工程应用能力与科学思维素养,为化工热力学核心概念的教学改革提供了可复制的实践范式。

关键词: 化工热力学, 逸度, 分子间作用力, 教学改革, 概念本质, 可视化教学

Abstract: Addressing the common challenges in teaching fugacity—a core concept in chemical thermodynamics—such as its abstract nature, fragmented understanding, and disconnection from practical applications, this study proposes a progressive teaching reform approach grounded in the dynamic interplay of intermolecular attraction and repulsion forces. Departing from the traditional linear teaching model of definition-derivation-exercise, this approach reconstructs a comprehensive cognitive framework encompassing microscopic molecular essence, macroscopic thermodynamic phenomena, quantitative mathematical expressions, and practical engineering applications. A series of visualized teaching aids were designed to facilitate deep integration of abstract thermodynamic concepts with students' prior knowledge of molecular physics. Teaching practice results demonstrate that this reform approach significantly improves students' correct understanding rate of fugacity's essential connotation from 38.2% to 92.7%, while markedly enhancing their engineering application skills and scientific thinking competencies. This study provides a replicable model for reforming the teaching of core concepts in chemical thermodynamics.

Key words: Chemical thermodynamics, Fugacity, Intermolecular force, Teaching reform, Conceptual essence, Visualized teaching