锰元素促进的人工合成化学及其应用

doi:10.3866/PKU.DXHX201909043

University Chemistry ›› 2019, Vol. 34 ›› Issue (12): 64-72.doi: 10.3866/PKU.DXHX201909043

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Manganese-Enabled Synthetic Chemistry and Applications

Xiwen YU^1,²,Yunhui YANG^1,^2,^3,*(),Congyang WANG^1,^2,^3,*()

¹ Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China
² University of Chinese Academy of Sciences, Beijing 100049, P. R. China
³ Physical Science Laboratory, Huairou National Comprehensive Science Center, Beijing 101400, P. R. China

Received:2019-09-26 Accepted:2019-10-28 Published:2019-11-11
Contact: Yunhui YANG,Congyang WANG E-mail:yangyh@iccas.ac.cn;wangcy@iccas.ac.cn
Supported by:
国家自然科学基金(21772202);国家自然科学基金(21831008);北京分子科学国家研究中心(BNLMS-CXXM-201901);北京怀柔综合性国家科学中心物质科学实验室(Z181100004218004)

Abstract

Abstract:

Photosynthesis is the most important synthetic reaction in nature, the O₂-evolution center of which contains the key Mn-O-Ca structure motif. Manganese features earth abundance, low toxicity, rich oxidative states, and unique reactivities, which makes it of great importance and hold huge potentials to achieve new synthesis unavailable by nature. In this paper, the history of manganese-enabled synthetic chemistry and its recent applications in inorganic electrochemistry and organic synthesis are reviewed briefly.

Key words: Manganese, Manganese oxides, Manganese carbonyl complexes, Synthetic chemistry

Xiwen YU,Yunhui YANG,Congyang WANG. Manganese-Enabled Synthetic Chemistry and Applications[J].University Chemistry, 2019, 34(12): 64-72.

Figures/Tables 15

References 24

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Manganese-Enabled Synthetic Chemistry and Applications

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