氢键有机框架——新型分子基晶态多孔材料

doi:10.12461/PKU.DXHX202601035

Abstract

Abstract: Hydrogen-bonded organic frameworks (HOFs) exhibit distinctive advantages such as mild synthesis conditions, remarkable structural designability, and superior environmental compatibility. These merits have established HOFs as prominent research focus in the field of porous materials. This review first outlines the developmental trajectory of HOFs, followed by a detailed discussion of their primary synthesis methodologies. Furthermore, it comprehensively summarizes recent advancements in HOF materials research, encompassing applications in gas adsorption and separation, fluorescence sensing, drug delivery, and water treatment. Finally, prospective research directions for HOF materials are proposed.

Key words: Crystalline material, Stability, Self-assembly, Application research, Design and synthesis

Zhengyi Di, Shuixiang Zou, Zhenyu Ji, Mingyan Wu. Hydrogen-bonded organic frameworks: novel molecule-based crystalline porous materials[J].University Chemistry, 2026, (): 2601035.

References

[1] M. Zhao, L. Sun, Y. Yang, X.-S. Gu, C.-J.-S. Lai, Coord. Chem. Rev. 2024, 514, 215881.
[2] 季者, 蓝光旭, 李江南, 杨四海. 大学化学, 2025, 40 (12), 70.
[3] Y. Sun, J. Wei, Z. Fu, M. Zhang, S. Zhao, G. Xu, C. Li, J. Zhang, T. Zhou, Adv. Mater. 2023, 35, 2208625.
[4] 林祖金, 曹荣. 化学学报, 2020, 78 (12), 1309.
[5] W. Wu, D. Chen, M. Zhang, X. Zhao, R. Zhao, C. Geng, J. Jia, G. Zhu, J. Am. Chem. Soc. 2025, 147, 2228.
[6] Y. Zhou, C. Chen, R. Krishna, Z. Ji, D. Yuan, M. Wu, Angew. Chem. Int. Ed. 2023, 62, e202305041.
[7] M. Mastalerz, I.M. Oppel, Angew. Chem. Int. Ed. 2012, 51, 5252.
[8] R.B. Lin, Y. He, P. Li, H. Wang, W. Zhou, B. Chen, Chem. Soc. Rev. 2019, 48, 1362.
[9] X. Song, Y. Wang, C. Wang, D. Wang, G. Zhuang, K.O. Kirlikovali, P. Li, O.K. Farha, J. Am. Chem. Soc. 2022, 144, 10663.
[10] C. Gu, A.B. Jia, Y.M. Zhang, S.X. Zhang, Chem. Rev. 2022, 122, 14679.
[11] C. Chen, L. Shen, H. Lin, D. Zhao, B. Li, B. Chen, Chem. Soc. Rev. 2024, 53, 2738.
[12] W. Wei, L. He, G. Han, Y. Lu, S. Shi, Z. Yuan, X. Wang, Y. Li, B. Chen, Z. Zhang, et al., Coord. Chem. Rev. 2024, 507, 215760.
[13] Z. Di, Y. Qi, X.-X. Yu, H.-R. Li, M.-X. Zuo, T.-T. Ren, C.-P. Li, Y. Zhao, Chem. Sci. 2024, 15, 16987.
[14] Y. He, S. Xiang, B. Chen, J. Am. Chem. Soc. 2011, 133, 14570.
[15] 杨奔, 沈淑坤, 金普军, 罗雨佳, 胡鉴勇. 大学化学, 2026, doi: 10.12461/PKU.DXHX202502128.
[16] Y.L. Li, E.V. Alexandrov, Q. Yin, L. Li, Z.B. Fang, W. Yuan, D.M. Proserpio, T.F. Liu, J. Am. Chem. Soc. 2020, 142, 7218.
[17] S. Lin, Y. Liang, P. Ke, L. Wang, D. Chen, L. Zhang, Y. He, Angew. Chem. Int. Ed. 2025, 64, e202500970.
[18] F. Hu, C. Liu, M. Wu, J. Pang, F. Jiang, D. Yuan, M. Hong, Angew. Chem. Int. Ed. 2017, 56, 2101.
[19] W. Yang, A. Greenaway, X. Lin, R. Matsuda, A.J. Blake, C. Wilson, W. Lewis, P. Hubberstey, S. Kitagawa, N.R. Champness, et al., J. Am. Chem. Soc. 2010, 132, 14457.
[20] H.L. Wang, B. Li, H. Wu, T.L. Hu, Z.Z. Yao, W. Zhou, S.C. Xiang, B.L. Chen, J. Am. Chem. Soc. 2015, 137, 9963.
[21] R. Zhang, C. Tang, S. Yang, P. Li, H. Han, Y. Wu, G. Wu, X. Zhao, B.-T. Liu, S.-N. Lei, et al., J. Am. Chem. Soc. 2025, 147, 16412.
[22] R. Zhang, H. Daglar, C. Tang, P. Li, L. Feng, H. Han, G. Wu, B. N. Limketkai, Y. Wu, S. Yang, et al., Nat. Chem. 2024, 16, 1982.
[23] S. Liu, L. Li, X.-Y. Gao, R. Cao, Y.-B. Zhang, T.-F. Liu, ACS Cent. Sci. 2025, 11, 1984.
[24] Y. Yang, L. Li, R. B. Lin, Y. Ye, Z. Yao, L. Yang, F. Xiang, S. Chen, Z. Zhang, S. Xiang, et al., Nat. Chem. 2021, 13, 933.
[25] S. Liu, X. Lian, B. Yue, S. Xu, G. Wu, Y. Chai, Y. Zhang, L. Li, J. Am. Chem. Soc. 2024, 146, 8335.
[26] J. Huang, Y. Li, H. Zhang, Z. Yuan, S. Xiang, B. Chen, Z. Zhang, Angew. Chem. Int. Ed. 2023, 62, e202315987.
[27] J. X. Wang, S. Xiong, X. W. Gu, H. M. Wen, X. Zhang, B. Chen, B. Li, G. Qian, Angew. Chem. Int. Ed. 2025, 64, e202515759.
[28] Z. Ji, Y. Zhou, R. Krishna, M. Hong, M. Wu, Angew. Chem. Int. Ed. 2025, 64, e202513398.
[29] L. Li, X. Zhang, X. Lian, L. Zhang, Z. Zhang, X. Liu, T. He, B. Li, B. Chen, X.-H. Bu, Nat. Chem. 2025, 17, 727.
[30] W. Wei, Y. Li, F. Yuan, Y. Lin, H. Lin, G. Han, B. Ma, Z. Yuan, S. Xiang, B. Chen, et al., Angew. Chem. Int. Ed. 2025, 64, e19313.
[31] Y. Su, Q. Gao, X. Ding, G. Ye, Angew. Chem. Int. Ed. 2025, 64, e202423932.
[32] Y. Li, H. Chen, J. Huang, H. Zhang, S. Lin, Z.-M. Ye, S. Xiang, B. Chen, Z. Zhang, J. Am. Chem. Soc. 2024, 146, 19425.
[33] T.-H. Chen, I. Popov, W. Kaveevivitchai, Y.-C. Chuang, Y.-S. Chen, O. Daugulis, A. J. Jacobson, O. Š. Miljanić, Nat. Commun. 2014, 5, 5131.
[34] D. Wang, Y. Zhao, Angew. Chem. Int. Ed. 2023, 62, e202217903.
[35] Q. Huang, Z. Xue, K. Segawa, T. Honda, T. Ogawa, C. Luo, H. Deng, Z. Chi, T. Fujikawa, K. Miyata, et al., J. Am. Chem. Soc. 2025, 147, 46234.
[36] Y. Wang, J. Yao, S. Wu, C. Zhi, L. Yin, Z. Song, J. Wang, L. Ling, Y. Ma, D. Zhang, et al., Chem 2025, 11, 102457.
[37] Y.-L. Li, J.-F. Lu, Q. Yin, L. Cai, H.-J. Jiang, C. Liu, G. Xu, T.-F. Liu, Angew. Chem. Int. Ed. 2025, 64, e202504396.
[38] J.-H. Zhang, Z.-M. Ge, J. Wang, D.-C. Zhong, T.-B. Lu, Nat. Commun. 2025, 16, 2448.
[39] Q. Zhou, Y. Guo, Y. Zhu, Nat. Catal. 2023, 6, 574.
[40] Y. Zhang, P. Li, P. Cui, X. Hu, C. Shu, R. Sun, M. Peng, B. Tan, X. Wang, Angew. Chem. Int. Ed. 2024, 63, e202413131.
[41] C. Wang, Z. Lv, Y. Liu, R. Liu, C. Sun, J. Wang, L. Li, X. Liu, X. Feng, W. Yang, et al., Angew. Chem. Int. Ed. 2024, 63, e202404015.
[42] W. Wang, Y. Shi, W. Chai, K.W. Tang, I. Pyatnitskiy, Y. Xie, X. Liu, W. He, J. Jeong, J.-C. Hsieh, et al., Nature 2025, 638, 401.
[43] L. Wu, X. Yang, H. Jia, L. Xiao, C. Gao, Z. Hu, J. Wang, Y. Guo, X. Wang, T. Liu, et al., Adv. Mater. 2024, 36, 2411229.
[44] X. Xu, B. Yan, Adv. Mater. 2023, 35, e2303410.
[45] R. Jiang, G. Luo, G. Chen, Y. Lin, L. Tong, A. Huang, Y. Zheng, Y. Shen, S. Huang, G. Ouyang, Sci. Adv. 2024, 10, eadp1796.
[46] X.-T. Jiang, Q. Yin, B.-T. Liu, J.-Y. Chen, R. Wang, T.-F. Liu, Nanoscale Adv. 2021, 3, 3441.
[47] Y. Sun, H. Sha, Y. Li, Y. Yan, W. Huang, T. Ouyang, L. Qin, S. Zhang, H. Huang, Q. Li, et al., Adv. Mater. 2025, 37, e09171.
[48] X. Yang, J. Huang, S. Gao, Y. Zhao, T. Huang, H. Li, T. Liu, Z. Yu, R. Cao, Adv. Mater. 2023, 35, 2305344.
[49] J. Liu, G. Mo, X. Gao, Y. Deng, Y. Wang, Q. Niu, Y. Lei, B. Fei, J. Yip, Z. Zhang, et al., Adv. Sci. 2025, e19971.

Hydrogen-bonded organic frameworks: novel molecule-based crystalline porous materials

PDF

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Recommended 0

[1]	Yafei Wang, Yan Zhang, Wei Li, Tingting Wang, Jiexuan Yang, Hui He, Ying Guan, Yongjun Zhang. The Secret Dance of Colors: Exploring How Colloidal Crystals Refract Beautiful Light and Shadows [J]. University Chemistry, 2026, 41(4): 417-423.
[2]	Wenjian Zhang, Mengxin Fan, Wenwen Fei, Wei Bai. Cultivation of Critical Thinking Ability: Based on RAFT Polymerization-Induced Self-Assembly [J]. University Chemistry, 2025, 40(4): 108-112.
[3]	Xiqing Liang, Tian Zhao, Jiawei Li, Haohui Tan, Hai Chen, Liyan Zeng. Pentaerythritol’s Journey of Making Friends [J]. University Chemistry, 2025, 40(10): 175-185.
[4]	Ruoxi Sun, Yiqian Xu, Shaoru Rong, Chunmiao Han, Hui Xu. The Enchanting Collision of Light and Time Magic: Exploring the Footprints of Long Afterglow Lifetime [J]. University Chemistry, 2024, 39(5): 90-97.
[5]	Shitao Fu, Jianming Zhang, Cancan Cao, Zhihui Wang, Chaoran Qin, Jian Zhang, Hui Xiong. Study on the Stability of Purple Cabbage Pigment [J]. University Chemistry, 2024, 39(4): 367-372.
[6]	Xuyang Wang, Jiapei Zhang, Lirui Zhao, Xiaowen Xu, Guizheng Zou, Bin Zhang. Theoretical Study on the Structure and Stability of Copper-Ammonia Coordination Ions [J]. University Chemistry, 2024, 39(3): 384-389.
[7]	Jin Tong, Shuyan Yu. Crystal Engineering for Supramolecular Chirality [J]. University Chemistry, 2024, 39(3): 86-93.
[8]	Jiaxi Xu, Yuan Ma. Influence of Hyperconjugation on the Stability and Stable Conformation of Ethane, Hydrazine, and Hydrogen Peroxide [J]. University Chemistry, 2024, 39(11): 374-377.
[9]	Chiyu Liang, Sihan Zhang, Chenxin Lu, Baolin Zhu, Xiaohang Qiu. Ultra-Fast Fabrication of Photonic Crystals Based on Silicon Dioxide [J]. University Chemistry, 2023, 38(4): 184-191.
[10]	Yanyuan Jia, Rong Rong, Jiaqi Ma, Shuo Guo. Distinctive Properties with the Same Ferrous Ion: FeSO₄∙7H₂O and (NH₄)₂Fe(SO₄)₂∙6H₂O: An Improvement of the Experiment on Preparation of Ferrous Ammonium Sulfate Hexahydrate [J]. University Chemistry, 2023, 38(11): 155-162.
[11]	Ligang Xu, Mingguang Li, Runfeng Chen. Fabrication and Performance Characteristics of Inverted Perovskite Solar Cells: Recommending a Comprehensive Chemistry Design Experiment [J]. University Chemistry, 2023, 38(11): 180-186.
[12]	Bin Zhang, Shuang Liu, Yanyan Zhu, Jiayuan Zhang, Min Wu, Chunmei Liu. Improvement and Optimization of Stoichiometric Ratio and Stability Constant Determination of Fe(phen)₃²⁺ Complex [J]. University Chemistry, 2022, 37(7): 2110066-.
[13]	Shuangshuang Cha, Jinpen Niu, Chuanfeng Liu, Jie Yan, Min Zhu, Wen Zhang, Mingyou Hu. Qualitative and Quantitative Determination of Melamine in Milk Powder Based on Supramolecular Self-Assembly Strategy [J]. University Chemistry, 2022, 37(5): 2111071-.
[14]	Min Peng, Jianxin Shi, Zhou Wang, Lianyun Li. Study about the Composition and Stability Constant of Sulfosalicylic Acid-Copper(Ⅱ) Complex by Mole Ratio Method [J]. University Chemistry, 2021, 36(8): 2009064-.
[15]	Lu Zhou. The Existence, Uniqueness and Stability of Chemical Equilibrium State [J]. University Chemistry, 2021, 36(12): 2102022-.