大学化学 >> 2025, Vol. 40 >> Issue (8): 376-387.doi: 10.12461/PKU.DXHX202411030

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2023年北京大学金秋营及第37届中国化学奥林匹克决赛磷团簇相关试题解析与拓展

周林锋1, 张玉林2, 林肃浩3, 朱龙观4   

  1. 1 浙江省富阳中学, 杭州 311400;
    2 浙江省衢州第二中学, 浙江 衢州 324000;
    3 浙江省杭州第二中学, 杭州 310053;
    4 浙江大学化学系, 杭州 310058
  • 收稿日期:2024-11-06 录用日期:2024-12-09 发布日期:2025-07-19
  • 通讯作者: 周林锋 E-mail:zhoulinfeng1018@163.com

Analysis and Expansion of Phosphorus Cluster-Related Problems in the 2023 Peking University Golden Autumn Camp and the 37th Chinese Chemistry Olympiad Finals

Linfeng Zhou1, Yulin Zhang2, Suhao Lin3, Longguan Zhu4   

  1. 1 Zhejiang Fuyang High School, Hangzhou 311400, China;
    2 Zhejiang Quzhou No. 2 High School, Quzhou 324000, Zhejiang Province, China;
    3 Zhejiang Hangzhou No. 2 High School, Hangzhou 310053, China;
    4 Department of Chemistry, Zhejiang University, Hangzhou 310058, China
  • Received:2024-11-06 Accepted:2024-12-09 Published:2025-07-19
  • Contact: Linfeng Zhou E-mail:zhoulinfeng1018@163.com

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摘要： 从结构化学与元素化学相融合的角度出发对2023年北京大学金秋营和第37届中国化学奥林匹克决赛中有关磷团簇的2道相关试题进行分析拓展。总结化学竞赛中对结构化学与元素化学内容考查的新动向，并针对未来化学竞赛教学提出建议。旨在帮助学生更好地理解磷团簇的结构特点，提高他们解决复杂化学问题的能力，并激发对化学学科的兴趣。

关键词: 高中化学竞赛, 结构化学, 元素化学, 磷团簇

Abstract: This article presents an analysis and expansion of two phosphorus cluster-related problems from the 2023 Peking University Golden Autumn Camp and the 37th Chinese Chemistry Olympiad Finals, from the perspective of integrating structural chemistry and elemental chemistry. The article summarizes emerging trends in the examination of structural and elemental chemistry in chemistry competitions and offers suggestions for future chemistry competition pedagogy. The goal is to assist students in better understanding the structural characteristics of phosphorus clusters, improve their ability to solve complex chemistry problems, and foster a greater interest in the field of chemistry.

Key words: High school chemistry competition, Structural chemistry, Elemental chemistry, Phosphorus cluster