大学化学 >> 2023, Vol. 38 >> Issue (10): 288-292.doi: 10.3866/PKU.DXHX202302012

化学实验 上一篇    下一篇

从燃烧热测量求算化学反应热——“燃烧热的测定”实验改进

江豪, 淳远(), 李唐, 张开宇, 杨立军, 高卫, 杨金月   

  • 收稿日期:2023-02-10 录用日期:2023-04-13 发布日期:2023-04-24
  • 通讯作者: 淳远 E-mail:ychun@nju.edu.cn
  • 基金资助:
    南京大学“百”层次优质课程建设;南京大学“十三五”实验教学改革研究课题;南京大学教学实验室建设提升计划;2021年度基础学科拔尖学生培养计划2.0研究课题(20212044)

Reaction Enthalpy Calculations via Heat of Combustion Determination: Modifying a Classic Experiment "Determining the Heat of Combustion"

Hao Jiang, Yuan Chun(), Tang Li, Kaiyu Zhang, Lijun Yang, Wei Gao, Jinyue Yang   

  • Received:2023-02-10 Accepted:2023-04-13 Published:2023-04-24
  • Contact: Yuan Chun E-mail:ychun@nju.edu.cn

摘要:

经典物理化学实验“燃烧热的测定”主要涉及化学热力学中燃烧热知识点,为典型的验证性实验。本实验改进结合重要化学品邻苯二甲酸(酐)的生产过程,通过测量萘、邻二甲苯、邻苯二甲酸和邻苯二甲酸酐等几种物质的燃烧热,计算其合成过程的反应热,既丰富了燃烧热实验的内容,又能和实际应用相关联。实验涉及几种原料廉价易得,均可测得准确的燃烧热数值,进而能获得可靠的反应热结果。采用线上、线下相结合的翻转学习教学模式,再通过几个反应过程测量的分工合作,可以有效地培养和提升学生的自主学习能力和团队协作精神。

关键词: 燃烧热, 化学反应热, 翻转学习, 实验改进

Abstract:

"Determining the heat of combustion" represents a familiar lab experiment that primarily provides a thermochemical understanding of combustion enthalpies. The experimental modification presented here is based on the practical production of commercial phthalic anhydride. Here, the reaction enthalpy is estimated by determining the heat of combustion of naphthalene, o-xylene, phthalic acid, and phthalic acid anhydride. This design may not only improve experimental contents but also strengthen practical applications of the heat of combustion. All required experimental reagents are cheap and readily available, and their heat of combustion can be measured accurately, making calculations of the overall reaction heat reliable. Moreover, a combined schedule of online and offline flipped learning will be implemented during the experiment; thus, enthalpy calculations for different reactions are expected to require cooperation among students. This modification may therefore be helpful for cultivating self-directed learning and teamwork among students.

Key words: Heat of combustion, Chemical reaction heat, Flipped learning, Improvement of experiment