高分子链结构的系统介绍

doi:10.3866/PKU.DXHX202401014

摘要/Abstract

摘要： 高分子链结构是衔接高分子化学和高分子物理的关键基础知识点。本文探讨了一种系统讲解高分子链结构的教学思路，从局部到整体依次介绍重复单元结构、键接序列结构、分子量及其分布、链拓扑构筑。这样的系统讲解将有助于学生把握高分子链结构的基本要素及其相应物理意义，从而更好地理解高分子化学结构与其物理性能之间的内在关系。

关键词: 链结构, 高分子, 教学

Abstract: Polymer chain structures form a crucial fundamental concept bridging polymer chemistry and polymer physics. This paper presents a systematic pedagogical approach to teaching polymer chain structures, hierarchically covering the structures of repeating units, bonding sequences, molecular weights and their distributions, and the topological architectures of chains. Such systematic introduction aims to enable students to grasp the fundamental structural elements of polymer chains and their corresponding physical significance. Consequently, it lays a solid foundation for students to better understand the intricate relationship between the chemical structures and the physical properties of polymers.

Key words: Chain structure, Polymer, Teaching

胡文兵. 高分子链结构的系统介绍[J]. 大学化学, 2024, (): 2401014.

Wen-Bing Hu. Systematic Introduction of Polymer Chain Structures[J]. University Chemistry, 2024, (): 2401014.

链接本文: https://www.dxhx.pku.edu.cn/CN/10.3866/PKU.DXHX202401014

https://www.dxhx.pku.edu.cn/CN/Y2024/V/I/2401014

参考文献

[1] Staudinger, H. Macromolecular Chemistry:Nobel Lecture; The Royal Swedish Academy of Sciences:Stockholm, Sweden, 1953.
[2] Jenkins, A. D.; Kratochvíl, P.; Stepto, R. F. T.; Suter, U. W. Pure Appl. Chem. 1996, 68, 2287.
[3] Staudinger, H. Chem. Ber. 1920, 53, 1073.
[4] Kuhn, W. Kolloid Z. 1934, 68, 2.
[5] Guth, E.; Mark, H. Monatsh. Chem. 1934, 65(1), 93.
[6] Flory, P. J. Nobel lecture:Spatial configuration of macromolecular chains. In Nobel Lectures, Chemistry 1971-1980; World Scientific:Singapore, 1993; p. 156.
[7] Rouse, P. E. A. J. Chem. Phys. 1953, 21, 1273.
[8] Wang, J.-P.; Yu, Y.-H.; Guo, Y.-Q.; Luo, W.; Hu, W.-B. Chin. J. Polym. Sci. 2021, 39, 906.
[9] De Gennes, P. G. J. Chem. Phys. 1971, 55, 572.
[10] Wang, J.-P.; Hu, W.-B. Chin. J. Polym. Sci. 2021, 39, 1496.
[11] Flory, P. J. Principles of Polymer Chemistry; Cornell University Press:Ithaca, NY, USA, 1953.
[12] Edwards, S. F. Proc. Phys. Soc. Lond. 1966, 88, 265.
[13] Rubinstein, M.; Colby, R. H. Polymer Physics; Oxford University Press:New York, NY, USA, 2003.
[14] De Gennes, P. G. Phys. Lett. A 1972, 38, 339.
[15] De Gennes, P. G. Scaling Concept in Polymer Physics; Cornell University Press:Ithaca, NY, USA, 1979.
[16] De Gennes, P. G. Rev. Mod. Phys. 1992, 64, 645.
[17] 胡文兵. 高分子物理导论. 现代化学基础丛书24卷,北京:科学出版社, 2011.
[18] Hu, W. Polymer Physics:A Molecular Approach; Springer-Verlag:Wien, Austria, 2013.
[19] Flory, P. J. Statistical Mechanics of Chain Molecules; Wiley Interscience:New York, NY, USA, 1969.
[20] Hu, W. B.; Frenkel, D. Adv. Polym. Sci. 2005, 191, 15.
[21] De Stefano, A. J.; Segalman, R. A.; Davidson, E. C. J. Am. Chem. Soc. Au 2021, 1(10), 1556.
[22] Ziegler, K. Consequences and Development of an Invention. In Nobel Lectures, Chemistry 1963-1970; Elsevier:Amsterdam, the Netherlands, 1972.
[23] Natta, G. From the Stereospecific Polymerization to the Asymmetric Autocatalytic Synthesis of Macromolecules. In Nobel Lectures, Chemistry 1963-1970; Elsevier:Amsterdam, the Netherlands, 1972.
[24] Hu, W.-B.; Mathot, V. B. F.; Alamo, R. G.; Gao, H.-H.; Chen, X.-J. Adv. Polym. Sci. 2017, 276, 1.
[25] 胡文兵. 中国科学:化学, 2023, 53(4), 606.
[26] Zheng, Y.; Pan, P. J. Prog. Polym. Sci. 2020, 109, 101291.
[27] Flory, P. J.; Vrij, A. J. Am. Chem. Soc. 1963, 85, 3548.
[28] Fox, T. G.; Flory, P. J. J. Appl. Phys. 1950, 21, 581.
[29] Hu, W. Phys. Repts. 2018, 747, 1.
[30] Hu, W.-B. J. Phys. Chem. B 2023, 127(4), 822.
[31] Smith, P.; Lemstra, P. J.; Pijper, J. P. L.; Kiel, A. M. Colloid Polym. Sci. 1981, 259, 1070.
[32] 周嘉嘉, 史安昌. 物理, 2023, 52(7), 493.
[33] Treloar, L. R. G. The Physics of Rubber Elasticity, 3rd edition; Clarendon Press:Oxford, England, UK, 1975.
[34] Gong, J. P. Soft Matter 2010, 6(12), 2583.