大学化学 >> 2026, Vol. 41 >> Issue (2): 178-189.doi: 10.12461/PKU.DXHX202502105

所属专题： 温室气体(CO2、CH4)化学

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二氧化碳向环状碳酸酯的“华丽转变”：催化剂种类与作用

杨佳艺1,2, 郝建秀1,2, 周华从1,2,3, 刘全生1,2   

  1. 1 内蒙古工业大学化工学院, 呼和浩特 010051;
    2 内蒙古自治区绿色化工重点实验室, 呼和浩特 010051;
    3 二氧化碳资源化利用自治区高等学校重点实验室, 呼和浩特 010051
  • 收稿日期:2025-02-20 录用日期:2025-03-10 发布日期:2025-12-27
  • 通讯作者: 郝建秀 E-mail:hjx2020@imut.edu.cn Jianxiu Hao
  • 基金资助:
    国家自然科学基金(22468036, 22468035, 22368038)；内蒙古工业大学研究生教育教学改革项目(YJG2024007)；内蒙古自治区自然科学基金杰出青年项目(2022JQ04)；内蒙古自治区自然科学基金青年项目(2024QN02018)；内蒙古自治区科技重大专项(2021ZD0020)；内蒙古工业大学科研启动金项目(BS2021018)

“Gorgeous Transformation” of Carbon Dioxide into Cyclic Carbonates: Catalyst Types and Roles

Jiayi Yang1,2, Jianxiu Hao1,2, Huacong Zhou1,2,3, Quansheng Liu1,2   

  1. 1 College of Chemical Engineering, Inner Mongolia University of Technology, Hohhot 010051, China;
    2 Inner Mongolia Key Laboratory of Green Chemical Engineering, Hohhot 010051, China;
    3. Key Laboratory of CO2 Resource Utilization at Universities of Inner Mongolia Autonomous Region, Hohhot 010051, China
  • Received:2025-02-20 Accepted:2025-03-10 Published:2025-12-27
  • Contact: Jianxiu Hao E-mail:hjx2020@imut.edu.cn

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摘要： 二氧化碳(CO2)的大量排放引发了一系列环境问题，但同时CO2也是一种重要的碳资源。因此，捕获CO2并将其转化为高附加值化学品，已成为科学与工业领域的热点课题。从化学角度而言，CO2被视作一种稳定、安全且储量丰富的C1资源。将CO2转化为高值化学品，不仅能有效解决CO2排放问题，同时实现了CO2的资源化利用。把CO2催化环化加成到环氧化物中，制备高附加值的环状碳酸酯，是一种反应过程简单且前景可观的CO2利用策略，该反应无副产物产生，原子经济性100%，反应条件温和。本文综述了CO2化学利用途径，着重介绍了CO2环加成反应高效催化剂，并对不同类型催化剂的性能进行了比较，最后对CO2环加成反应研究进展进行了总结与展望。

关键词: 二氧化碳, 环氧化物, 环状碳酸酯, 催化剂

Abstract: The massive emission of carbon dioxide (CO2) has led to a series of environmental challenges; however, CO2 is also a valuable carbon resource. As a result, capturing CO2 and converting it into high-value chemicals has become an urgent area of research in both science and industry. Chemically, CO2 is considered a stable, safe, and abundant C1 resource. Converting CO2 into high-value chemicals not only addresses the issue of CO2 emissions but also facilitates its resource utilization. Among the various methods, the catalytic addition of CO2 to epoxides for the preparation of high-value cyclic carbonates is a promising strategy for CO2 utilization. This process is atomically efficient (100%), generates no by-products, and operates under mild reaction conditions. This review discusses the chemical utilization pathways of CO2, emphasizes efficient catalysts for the CO2 cycloaddition reaction, compares the catalytic activities of different types of catalysts, and concludes with a summary and outlook on the progress in CO2 cycloaddition research.

Key words: Carbon dioxide, Epoxide, Cyclic carbonate, Catalyst