方寸之间，大放“光”彩——介绍一个中级分析化学实验

doi:10.3866/PKU.DXHX202208121

Abstract

Abstract:

An analytical chemistry experiment at an intermediate level is presented in this work, achieving the detection of chemiluminescence (CL) on a paper-based device. Using copper nitrate and benzene-1, 3, 5-tricarboxylic (BTC) acid in a metal-organic frameworks (MOFs) synthesis reaction, Cu-BTC with a catalytic effect was synthesized and loaded onto the paper's surface. Due to the catalytic effect of Cu-BTC in a luminol-H₂O₂ CL system, trace H₂O₂ can be detected. This exercise can train students' practical ability in comprehensive experiments. It can also improve the intuitive ability of normal students to better grasp experimental data processing.

Key words: Chemiluminescence, Paper-based device, Hydrogen peroxide, Metal organic frameworks

Qian Hu, Xinyi Li, Ye Yuan, Xu Han, Xiaosong Qi, Jiaqi Li, Yanli Guo, Xiaohu Ma, Wei Liu. Send out "Light" Brilliance within Square Inches: Introducing an Analytical Chemistry Experiment at an Intermediate Level[J].University Chemistry, 2023, 38(8): 101-107.

Figures/Tables 7

References 17

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试剂名称	纯度/型号	厂家
鲁米诺	分析纯AR	Sigma公司
无水乙醇	分析纯AR	国药集团化学试剂有限公司
过氧化氢水溶液	分析纯AR	国药集团化学试剂有限公司
Cu(NO₃)₂∙3H₂O	分析纯AR	国药集团化学试剂有限公司
N, N-二甲基甲酰胺(DMF)	分析纯AR	国药集团化学试剂有限公司
1, 3, 5-均苯三甲酸(H₃BTC)	分析纯AR	国药集团化学试剂有限公司
Waterman 1号滤纸	200.0 mm × 200.0 mm	Sigma公司

仪器名称	型号	厂家
超纯水机	1810B	重庆摩尔水处理设备有限公司
高速离心机	4-20R	西安惜诺实验室设备有限公司
电热鼓风干燥箱	101	上海一恒科学仪器有限公司
超声波清洗器	KH5200E	昆山禾创超声仪器有限公司
X射线粉末衍射仪(XRD)	D8 Advance X	德国布鲁克公司
场发射扫描电子显微镜(SEM)	SU8220	日本日立公司
多功能化学发光分析检测系统	MPI-B	西安瑞迈分析仪器有限公司

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Send out "Light" Brilliance within Square Inches: Introducing an Analytical Chemistry Experiment at an Intermediate Level

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References 17

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