“受阻Lewis酸碱对”化学的研究进展

doi:10.3866/PKU.DXHX20160401

Abstract

Abstract:

Frustrated Lewis Pairs (FLPs) represent a class of Lewis acids and bases possessing unique reactivities. Since their discovery, FLPs have obtained extensive attention and have grown rapidly on a broad range of studies. This paper highlights the application of FLPs in the fields of asymmetric hydrogenation, polymerization and catalytic reduction of CO₂. Transition-metal FLPs and complexes containing FLPs ligands are also reviewed. Finally the trend in the development of FLPs is also discussed.

Key words: Frustrated Lewis Pairs, Asymmetric hydrogenation, Ionic polymerization, Catalytic CO₂ reduction, Transition-metal catalytic systems

Han-Yu LIU,Zhong-Tian YANG,Zi-Di YU,Tian-Xiong MI,Jiang BIAN. Research Progress on Frustrated Lewis Pairs Chemistry[J].University Chemistry, 2016, 31(4): 1-11.

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Research Progress on Frustrated Lewis Pairs Chemistry

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