功能化金属有机骨架材料在放射性离子检测中的应用

doi:10.3866/PKU.DXHX201910053

Abstract

Abstract:

With the shortage of fossil energy and increasing environmental pollution, nuclear energy has received extensive attention by its virtue of high energy density and low emission of greenhouse gases. However, radioactive nuclear waste remains a serious task for its safe and effective disposal due to their harmful effects on human health and the environment. As a new type of multifunctional nanomaterial, metal-organic frameworks (MOFs) are synthesized via the self-assembling combination of inorganic metals and organic ligands. Compared with traditional porous materials, MOFs have broad application prospects in the adsorption and detection of radioactive ions. In this paper, we reviewed the functional modification strategies of MOFs and summarized the progress in the applications of functionalized MOFs in removal and fluorescence sensing of contaminated ions in recent years. Besides, the future development trends are also discussed.

Key words: Metal-organic frameworks, Radioactive ions, Functionalization, Fluorescence sensing, Absorption

Wei Wei, Yan Xia. Application of Functionalized Metal-Organic Frameworks in Radioactive Ions Detection[J].University Chemistry, 2020, 35(12): 192-200.

Figures/Tables 6

References 69

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Targets	MOF-based materials	Adsorption capacity/(mg?g^?1)	Equilibrium time	Mechanism	Ref.
ReO₄^?	SCU-100	541	2 h	Ion-exchange	[31]
ReO₄^?	SLUG-21	602	－	Ion-exchange	[33]
ReO₄^?	UiO-66-NH2	159	24 h	Ion-exchange	[34]
ReO₄^?	SBN	786	2 h	Ion-exchange	[35]
ReO₄^?	SCU-101	217	10 min	Ion-exchange	[36]
ReO₄^?	IPM-206	195	－	Ion-exchange	[37]
TcO₄^?	NDTB-1	－	> 36 h	Ion-exchange	[38]
Ba²⁺	MOF-808-SO₄	131.1	< 250 min	Binding with sulfate group	[39]
Ba²⁺	MIL-101Cr-SO₃H	70.5	< 250 min	Chelate with sulfonic group	[39]
Cs⁺	MOF/KNiFC	153	45 min	Ion-exchange chemisorption	[40]
Cs⁺	3D uranyl organic framework	432	20 min	Ion-exchange	[41]
U⁴⁺	nZVI@MOF-74	348	2 h	Electrostatic interaction	[42]
U⁴⁺	UiO-66-neomycin	296	12 h	Interaction with anti-biofouling	[43]
U⁴⁺	UiO-66-AO	194.8	13 h	Electrostatic interaction	[44]
U⁴⁺	JXNU-4	121.2	35 min	Coordination	[45]
Co²⁺	UiO-66-COOCH₃	334.4	24 h	Coordination	[46]
Co²⁺	UiO-66-CONH₂	339.7	24 h	Coordination	[46]
Co²⁺	UiO-66-Schiff base	256	5 h	Coordination	[47]
Th⁴⁺	SCU-3	－	－	Coordination ion-exchange	[48]
Th⁴⁺	UiO-66-(COOH)₂	350	30 min	Coordination	[49]
Th⁴⁺	MIL-100(Al)	167	15 min	Chemisorption	[50]
Th⁴⁺	DMn-MOF	46.3	－	－	[51]
Sr²⁺	MOF-808-C₂O₄	206.3	120 min	Chemisorption	[52]
Pd²⁺	ASUiO-66	45.4	－	Acting with sulfur and alkene	[53]
Eu³⁺	azofunctionalized anionic UOF	－	120 min	Ion-exchange	[54]
Eu³⁺	HKUST-1@H₃PW₁₂O₄₀	14.58	120 min	Coordination with ligands	[55]

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Application of Functionalized Metal-Organic Frameworks in Radioactive Ions Detection

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