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Comprehensive experimental teaching design for chemical technology from the perspective of science-education integration: halogen-functionalized porous organic cages for SO2 adsorption

Mingxuan Liu1, Wenguan Wu1, Ailan Liu1, Shiqi Sun1, Lingxin Zhang1, Borui Li1, Hui Li1, Xiangjun Chen2, Changyan Li1, Xiongli Liu1   

  1. 1 College of Chemistry and Chemical Engineering, Ministry of Education Engineering Research Center for Dairy Quality and Safety Control Technology, Inner Mongolia University, Hohhot 010021, Inner Mongolia Autonomous Region, China;
    2 Affiliated Middle School of Inner Mongolia Normal University, Hohhot 010022, Inner Mongolia Autonomous Region, China
  • Received:2026-07-29 Accepted:2026-09-09
  • Contact: Changyan Li, Xiongli Liu E-mail:celicy@imu.edu.cn;xiongliliu@imu.edu.cn

Abstract: Chemical Technology is a core course in chemical engineering and technology programs, however, its instruction has long emphasized process simulation at the expense of material innovation, making it difficult for students to connect process design with advances in functional materials. Guided by the concept of science-education integration, this study transforms an undergraduate thesis research outcome-the synthesis of a halogen-functionalized porous organic cage, Inner Mongolia University Porous Organic Cage-Cl (IMUPOC-Cl), and its performance in SO2 adsorption and separation-into a comprehensive experimental design. Centered on the core process engineering question of adsorbent design and selection for flue gas desulfurization, the design comprises four progressive modules: material creation, structural elucidation, performance evaluation and process trade-off analysis. Through a halogen functionalization strategy, students enhance the material's SO2 adsorption capacity, measure adsorption isotherms at different temperatures, calculate the adsorption enthalpy, compare the results with those of the non-functionalized material and with CO2 adsorption behavior, and thereby assess the material’s hydrophobicity in relation to process conditions for high-humidity flue gas. Teaching practice shows that this case effectively bridges the cognitive gap between molecular design and process flowsheets and cultivates students’ ability to pursue process innovation from the functional materials perspective.

Key words: Chemical technology, Research-education integration, Porous organic cages, Sulfur dioxide adsorption, Regional air pollution