University Chemistry ›› 2026, Vol. 41 ›› Issue (2): 190-196.doi: 10.12461/PKU.DXHX202503006

Special Issue:

• Survey of Chemistry • Previous Articles     Next Articles

Electrochemical Carbon Dioxide Reduction to Ethylene

Yucai Zhang1, Jun Jiang2,3   

  1. 1 Hefei National Laboratory for Physical Sciences at the Microscale (University of Science and Technology of China), Hefei 230026, China;
    2 School of Chemistry and Materials Science, University of Science and Technology of China, Hefei 230026, China;
    3 National Demonstration Center for Experimental Chemistry Education (University of Science and Technology of China), Hefei 230026, China
  • Received:2025-03-03 Accepted:2025-03-25 Published:2025-12-27
  • Contact: Jun Jiang E-mail:jiang123@ustc.edu.cn

Abstract: The increasingly severe “greenhouse effect” has made the resource utilization of carbon dioxide (CO2) an urgent priority. Compared to other alternative approaches, electrochemical CO2reduction to high-value-added fuels and chemicals powered by renewable electricity offers advantages such as mild operating conditions, environmental friendliness, and high efficiency. This review focuses on CO2-to-ethylene conversion, as ethylene has the largest market demand among CO2reduction products. We first provide a brief introduction to the fundamental reaction mechanisms. Next, we discuss advanced catalyst modification strategies and introduce four representative electrolyzers. We then summarize the current progress in CO2-to-ethylene conversion and highlight the existing scientific and technological challenges. Finally, we conclude with an outlook on the industrial application prospects of CO2-to-ethylene conversion.

Key words: Electrocatalysis, CO2 reduction, Ethylene