University Chemistry ›› 2024, Vol. 39 ›› Issue (11): 374-377.doi: 10.3866/PKU.DXHX202402049

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Influence of Hyperconjugation on the Stability and Stable Conformation of Ethane, Hydrazine, and Hydrogen Peroxide

Jiaxi Xu1, Yuan Ma2   

  1. 1 College of Chemistry, Beijing University of Chemical Technology, Beijing 100029, China;
    2 Department of Chemistry, Tsinghua University, Beijing 100084, China
  • Received:2024-02-23 Accepted:2024-04-03 Published:2024-11-09
  • Contact: Jiaxi Xu E-mail:jxxu@mail.buct.edu.cn

Abstract: Ethane, hydrazine, and hydrogen peroxide are three structurally similar substances composed of the elements from the same period with hydrogen, respectively. However, their stability significantly decreases in a sequential manner, and their stable conformations are also dissimilar. These differences have not been explained adequately in the current textbooks. This article provides a possible explanation for the variation in stability among these substances by analyzing their n-σ* hyperconjugation. Additionally, it elucidates the absence of anti-conformation in hydrazine and hydrogen peroxide. The hyperconjugation theory is extended to illustrate and to discuss stability and stable conformation of inorganic compounds.

Key words: Ethane, Hydrazine, Hydrogen peroxide, Stability, Conformation, Hyperconjugation