构建分子基材料新方式——2025年诺贝尔化学奖浅谈

doi:10.12461/PKU.DXHX202511097

Abstract

Abstract: The 2025 Nobel Prize in Chemistry was awarded to three notable inorganic chemists—Susumu Kitagawa, Richard Robson, and Omar M. Yaghi—in recognition of their groundbreaking contributions to the establishment of Metal-Organic Frameworks (MOFs). MOFs are crystalline materials constructed by the precise assembly of metal nodes and organic ligands via coordination bonds, resulting in frameworks with exceptionally high specific surface areas, permanent porosity and ability to insert functional groups in a periodic manner. This unique architecture endows them with tremendous potential for applications in gas storage, separation and catalysis. This article reviews the development of MOFs from conceptual inception to material maturity, elucidates their key structural features and underlying synthetic philosophy, and briefly highlights the foundational contributions of Chinese scientists to this field.

Key words: MOFs, Coordination chemistry, Crystal engineering, Porous materials, Gas sorption

Zhe Ji, Guangxu Lan, Jiangnan Li, Sihai Yang. A New Protocol to Construct Molecular Materials: A Brief Introduction on the 2025 Nobel Prize in Chemistry[J].University Chemistry, 2025, 40(12): 70-77.

References

[1] Hoskins, B. F.; Robson, R. J. Am. Chem. Soc. 1989, 111, 5962.
[2] Hoskins, B. F.; Robson, R. J. Am. Chem. Soc. 1990, 112, 1546.
[3] Kondo, M.; Yoshitomi, T.; Matsuzaka, H.; Kitagawa, S.; Seki, K. Angew. Chem. Int. Ed. 1997, 36, 1725.
[4] Li, H.; Eddaoudi, M.; Groy, T. L.; Yaghi, O. M. J. Am. Chem. Soc. 1998, 120, 8571.
[5] Yaghi, O. M.; Li, G.; Li, H. Nature 1995, 378, 703.
[6] 游效曾. 配位化合物的结构与性质. 北京: 科学出版社, 1992.
[7] 游效曾. 分子材料: 光电功能化合物. 上海: 上海科学技术出版社, 2001.
[8] Tian, Y.; Cai, C.; Ji, Y.; You, X.; Peng, S.; Lee, G. Angew. Chem. Int. Ed. 2002, 41, 1384.
[9] Xiong, R.; Xue, X.; Zhao, H.; You, X.; Abrahams, B.; Xue, Z. Angew. Chem. Int. Ed. 2002, 41, 3800.
[10] Yao, T.; Zuo, J.; You, X.; Huang, X. Polyhedron 1995, 14, 1487.
[11] You, X.; Duan, C. Chem. Mater. 1997, 9, 2687.
[12] Song, X.; Muddassir, M.; Chen, Y.; Wang, H.; Song, Y.; You, X. Dalton Trans. 2013, 42, 1116.
[13] Hong, M.; Lei, X.; Huang, Z.; Kang, B.; Jiang, F.; Liu, H. Chin. Sci. Bul. 1993, 38, 912.
[14] Hong, M.; Su, W.; Cao, R.; Zhang, W.; Lu, J. Inorg. Chem. 1999, 38, 600.
[15] Su, W.; Cao, R.; Hong, M.; Chen, J.; Lu, J. Chem. Commun. 1998, 1389.
[16] Su, W.; Hong, M.; Weng, J.; Cao, R.; Lu, S. Angew. Chem. Int. Ed. 2000, 39, 2911.
[17] Hong, M.; Zhao, Y.; Su, W.; Cao, R.; Fujita, M.; Zhou, Z.; Chan, A. J. Am. Chem. Soc. 2000, 122, 4819.
[18] Hong, M.; Zhao, Y.; Su, W.; Cao, R.; Fujita, M.; Zhou, Z.; Chan, A. Angew. Chem. Int. Ed. 2000, 39, 2468.
[19] Liang, Y.; Cao, R.; Su, W.; Hong, M.; Zhang, W. Angew. Chem. Int. Ed. 2000, 39, 3304.
[20] Chen, X.; Aubin, S. M. J.; Wu, Y.; Yang, Y.; Mak, T. C.W.; Hendrickson, D. N. J. Am. Chem. Soc. 1995, 117, 9600.
[21] Tong, M.; Chen, X.; Ye, B.; Ji, L. Angew. Chem. Int. Ed. 1999, 38, 2237.
[22] Zhang, X.; Tong, M.; Chen, X. Angew. Chem. Int. Ed. 2002, 41, 1029.
[23] Zheng, S.; Zhang, J.; Wong, W.; Chen, X. J. Am. Chem. Soc. 2003, 125, 6882.
[24] Huang, X.; Lin, Y.; Zhang, J.; Chen, X. Angew. Chem. Int. Ed. 2006, 45, 1557.
[25] Zhang, J.; Zhou, H.; Zhou, D.; Mo, Z.; Lin, R.; Liao, P.; He, C.; Zhang, W.; Chen, X. Adv. Mater. 2018, 30, 174350.
[26] Ma, B.; Zhang, D.; Gao, S.; Jin, T.; Yan, C.; Xu, G. Angew. Chem. Int. Ed. 2000, 39, 3644.
[27] Jiang, S.; Wang, B.; Su, G.; Wang, Z.; Gao, S. Angew. Chem. Int. Ed. 2010, 49, 7448.
[28] Liu, J.; Chen, Y.; Liu, J.; Vieru, V.; Jia, J.; Chibotaru, F.; Lan, Y.; Wernsdorfer, W.; Gao, S. J. Am. Chem. Soc. 2016, 138, 5441.
[29] Weng, D.; Wang, Z.; Gao, S. Chem. Soc. Rev. 2011, 40, 3157.
[30] Xu, G.; Zhang, W.; Ma, X.; Chen, Y.; Zhang, L.; Cai, H.; Wang, Z.; Xiong, R.; Gao, S. J. Am. Chem. Soc. 2011, 133, 14948.
[31] Liu, B.; Shang, R.; Hu, K.; Wang, Z.; Gao, S. Inorg. Chem. 2012, 51, 13363.
[32] Bu, X.; Chen, W.; Lu, S.; Zhang, R.; Liao, D.; Bu, W.; Shionoya, M.; Brisse, F.; Ribas, J. Angew. Chem. Int. Ed. 2001, 40, 3201.
[33] Bu, X.; Tong, M.; Chang, H.; Kitagawa, S.; Batten, S. Angew. Chem. Int. Ed. 2004, 43, 192.
[34] Tian, D.; Chen, Q.; Li, Y.; Zhang, Y.; Chang, Z.; Bu, X. Angew. Chem. Int. Ed. 2014, 53, 837.

A New Protocol to Construct Molecular Materials: A Brief Introduction on the 2025 Nobel Prize in Chemistry

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