高电压水系二次电池设计新策略

doi:10.3866/PKU.DXHX202202072

Abstract

Abstract:

Limited by the decomposition voltage of water (1.23 V), the open-circuit voltage of aqueous secondary batteries is generally low. Through the analysis of factors influencing the open-circuit voltage of aqueous secondary batteries, several new strategies to improve the open-circuit voltage are introduced in this paper. In addition, the advantages and disadvantages of each strategy are discussed.

Key words: Aqueous secondary battery, High voltage, Design strategy

Linghao Su, Liangyu Gong, Chuanli Ma, Dongqi Dong, Jie Wang, Cuijuan Xuan. New Design Strategies for High-Voltage Aqueous Secondary Batteries[J].University Chemistry, 2023, 38(1): 280-286.

Figures/Tables 7

References 26

1	王新平;王旭珍;任素贞;王新葵;吕哲.大学化学,2016,31(6),67.
2	李荻.电化学原理,第3版北京:北京航空航天大学出版社,2013,249
3	邓玲娟.大学化学,2022,37(6),2107049.
4	SuoL.;BorodinO.;GaoT.;OlguinM.;HoJ.;FanX.;LuoC.;WangC.;XuK.Science2015,350(6263),938. doi: 10.1126/science.aab1595
5	WangF.;SuoL.;LiangY.;YangC.;HanF.;GaoT.;SunW.;WangC.Adv. Energy Mater.2017,7(8),1600922. doi: 10.1002/aenm.201600922
6	GuS.;GongK.;YanE. Z.;YanY.Energy Environ. Sci.2014,7(9),2986. doi: 10.1039/C4EE00165F
7	ChenL.;GuoZ.;XiaY.;WangY.Chem. Commun.2013,49(22),2204. doi: 10.1039/c3cc00064h
8	YadavG. G.;TurneyD.;HuangJ.;WeiX.;BanerjeeS.ACS Energy Lett.2019,4(9),2144. doi: 10.1021/acsenergylett.9b01643
9	LiuC.;ChiX.;HanQ.;LiuY.Adv. Energy Mater.2020,10(12),1903589. doi: 10.1002/aenm.201903589
10	ChaoD.;YeC.;XieF.;ZhouW.;ZhangQ.;GuQ.;DaveyK.;GuL.;QiaoS.-Z. Adv. Mater.2020,32(25),2001894. doi: 10.1002/adma.202001894
11	ZhongC.;LiuB.;DingJ.;LiuX.;ZhongY.;LiY.;SunC.;HanX.;DengY.;ZhaoN.;HuW.Nat. Energy2020,5(6),440. doi: 10.1038/s41560-020-0584-y
12	GaoT.;SunY.;GongL.;MaC.;WangJ.;SuL. J.Electrochem. Soc.2020,167(2),020552. doi: 10.1149/1945-7111/ab6f58
13	XuY.;CaiP.;ChenK.;DingY.;ChenL.;ChenW.;WenZ.Angew. Chem. Int. Ed.2020,59(52),23593. doi: 10.1002/anie.202012017
14	WuH.;LiuS.-J.;LianK. J.Energy Storage2020,29,101305. doi: 10.1016/j.est.2020.101305
15	洪为臣;雷青;马洪运;王保国.化工进展,2016,35(2),445.
16	ChenW.;LiG.;PeiA.;LiY.;LiaoL.;WangH.;WanJ.;LiangZ.;ChenG.;ZhangH.;et alNat. Energy2018,3(5),428. doi: 10.1038/s41560-018-0147-7
17	ChaoD.;ZhouW.;YeC.;ZhangQ.;ChenY.;GuL.;DaveyK.;QiaoS.-Z.Angew. Chem. Int. Ed.2019,58(23),7823. doi: 10.1002/anie.201904174
18	HeS.;WangJ.;ZhangX.;ChenJ.;WangZ.;YangT.;LiuZ.;LiangY.;WangB.;LiuS.;et alAdv. Func. Mater.2019,29(45),1905228. doi: 10.1002/adfm.201905228
19	HuangJ.;GuoZ.;DongX.;BinD.;WangY.;XiaY.Sci. Bull.2019,64(23),1780. doi: 10.1016/j.scib.2019.09.020
20	LiangG.;MoF.;LiH.;TangZ.;LiuZ.;WangD.;YangQ.;MaL.;ZhiC.Adv. Energy Mater.2019,9(32),1901838. doi: 10.1002/aenm.201901838
21	HuangJ.;YanL.;BinD.;DongX.;WangY.;XiaY. J.Mater. Chem. A2020,8(12),5959. doi: 10.1039/D0TA01484B
22	WangM.;ZhengX.;ZhangX.;ChaoD.;QiaoS.-Z.;AlshareefH. N.;CuiY.;ChenW.Adv. Energy Mater.2021,11(5),2002904. doi: 10.1002/aenm.202002904
23	WeiL.;ZengL.;WuM. C.;JiangH. R.;ZhaoT. S. J.Power Sources2019,423,203. doi: 10.1016/j.jpowsour.2019.03.085
24	LiangG.;MoF.;LiH.;TangZ.;LiuZ.;WangD.;YangQ.;MaL.;ZhiC.Adv. Energy Mater.2019,9(32),1901838. doi: 10.1002/aenm.201901838
25	XieM.;KongS.;SuL.ChemElectroChem2022,9(2),e202101529.
26	LuJ. M.;DreisingerD.;GluckT.Hydrometallurgy2014,141,105. doi: 10.1016/j.hydromet.2013.11.002

正极	负极	电解质	电池电压/V	文献
Ce⁴⁺/Ce³⁺	Zn²⁺/Zn	NaOH/NaClO₄/HClO₄	3.08	[6]
MnO₄⁻/MnO₂	Zn²⁺/Zn	KOH + LiOH/KMnO₄ + H₂SO₄	2.8	[7]
MnO₄⁻/MnO₂	Zn²⁺/Zn	凝胶KOH/KMnO₄ + H₂SO₄	2.8	[8]
MnO₂/Mn²⁺	Zn²⁺/Zn	凝胶KOH/H₂SO₄ + MnSO₄	2.45	[8]
MnO₂/Mn²⁺	Zn²⁺/Zn	KOH+Zn(Ac)₂//H₂SO₄ + MnSO₄	2.44	[9]
MnO₂/Mn²⁺	Zn²⁺/Zn	NaOH+ZnO//H₂SO₄ + MnSO₄ + NiSO₄	2.442	[10]
MnO₂/Mn²⁺	Zn²⁺/Zn	KOH/K₂SO₄/H₂SO₄	2.83	[11]
PbO₂/Pb²⁺	Zn²⁺/Zn	KOH/K₂SO₄/H₂SO₄	2.8	[12]
PbO₂/Pb²⁺	Zn²⁺/Zn	KOH/K₂SO₄/H₂SO₄	3.09	[13]
PbO₂/Pb²⁺	Zn²⁺/Zn	KOH/K₂SO₄/H₂SO₄	2.8	[14]

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New Design Strategies for High-Voltage Aqueous Secondary Batteries

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