联用技术应用于元素形态分析

doi:10.3866/PKU.DXHX202211088

Abstract

Abstract:

This paper investigates the significance of element speciation analysis, the various hyphenated techniques used in element speciation analysis, and their application in real samples. This involves a variety of separation technologies, such as high-performance liquid chromatography, ion chromatography, size exclusion chromatography, gas chromatography, and capillary electrophoresis, as well as various detection methods, such as inductively coupled plasma mass spectrometry, inductively coupled plasma optical emission spectrometry, atomic fluorescence spectrometry, and atomic absorption spectrometry. Based on this, we developed teaching experiments, combined theory with practice, and further strengthened students' understanding, mastery, and application of knowledge.

Key words: Hyphenated technique, Speciation analysis, Teaching experiment

Anna Tang, Yiling Shi, Jin Du, Deming Kong. Application of Hyphenated Technique in Element Speciation Analysis[J].University Chemistry, 2023, 38(9): 98-104.

Figures/Tables 1

References 31

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分离模式	联用技术	元素形态	实际样品	参考文献
液相色谱	HPLC-ICP-MS	As、Hg、Se、Cr、Pb等元素的不同形态	鱼肉、土壤、水样、尿液、血清等	[3–5]
	HPLC-MIP-OES	Fe(Ⅱ)、Fe(Ⅲ)、Se的不同形态	沉积物、土壤	[8]
	HPLC-AFS	As、Se、Hg的形态	水样、血液	[11, 12]
	HPLC-AAS	Hg形态	鱼肉	[13]
	SEC-ICP-MS	Hg键合蛋白	金枪鱼、蛙鱼	[7]
	IC-ICP-MS	As、Hg、Se、Cr、Sb的不同形态	废水、土壤、鱼肉、尿液、血清等	[6]
	IC-ICP-OES	Se、Cr	沉积物、矿泉水样	[9, 10]
	IC-AFS	As、Se的不同形态	人体尿液、药物	[14]
气相色谱	GC-ICP-MS	Hg、As、Se、Sb、Cr、Sn等元素的不同形态	浮游生物、水样、沉积物、土壤、废弃物、生物样品	[15, 16]
	GC-AFS	Hg、As、Se、Sn不同形态	沉积物、浮游生物	[17–19]
	GC-ICP-OES	Sn形态	沉积物	[20]
毛细管电泳	CE-ICP-MS	As、Se、Cr、Hg、Pb的不同形态	食品、藻类、鱼类、水样	[21, 22]
	CE-AAS	Hg、Cd不同形态	鱼肉、生物样品	[23]
	CE-AFS	As、Se、Hg不同形态	水、土壤、空气、生物群、食物	[24, 25]
	CE-ICP-OES	Ca、Mg不同形态	血浆	[26, 27]
芯片电泳	Chip-AFS	As、Hg不同形态	生物样品、环境水样	[28, 29]
流动注射	FI-HG-ICP-OES	Se形态	水果、饮料、葡萄酒、茶叶	[30]

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Application of Hyphenated Technique in Element Speciation Analysis

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