大学化学

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点卤之谜:大豆胶体的华丽蜕变

王子怡1, 刘叙言1, 蒋海英2   

  1. 1 西北大学食品科学与工程学院, 陕西 西安 710069;
    2 西北大学化学与材料科学学院, 教育部合成与天然功能分子重点实验室, 陕西 西安 710127
  • 收稿日期:2026-04-29 录用日期:2026-07-13
  • 通讯作者: 蒋海英 E-mail:jianghy@nwu.edu.cn Hai-Ying Jiang

The mystery of bittern curdling: a magnificent transformation of soy colloids

Ziyi Wang1, Xuyan Liu1, Hai-Ying Jiang2   

  1. 1 College of Food Science and Technology, Northwest University, Xi'an 710069, ShaanXi Province, China;
    2 Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an 710127, Shaanxi Province, China
  • Received:2026-04-29 Accepted:2026-07-13
  • Contact: Hai-Ying Jiang E-mail:jianghy@nwu.edu.cn

摘要: 豆腐是中国人的发明,也是中国餐桌上最朴素的哲学。从街头巷尾滑嫩的豆腐花,到家常餐桌细腻的嫩豆腐,再到煎炒烹炸皆宜的劲道老豆腐,这些形态各异的豆腐美食,实则源于同一场神奇的蜕变。本文以老豆腐、嫩豆腐和豆腐花为切入点,揭示从黄豆到豆腐的神奇蜕变背后隐藏的物理化学原理。豆浆作为蛋白质胶体体系,其稳定性源于胶粒表面的电荷排斥与水化膜保护;而“点卤”过程本质上是电解质诱导的胶体聚沉。通过调控凝固剂种类与浓度,我们可以精准打造从细腻豆花到劲道老豆腐的丰富质地。本文揭示了传统豆腐制作中蕴含的科学原理,展现了物理化学与日常饮食实践之间错综复杂的关联,也展现了我们对文化遗产的理解与欣赏。

关键词: 豆腐, 点卤, 胶体, 聚沉, 凝固

Abstract: Tofu, a quintessential Chinese invention, embodies both a fundamental element of Chinese culinary tradition and a profound representation of philosophical simplicity on the Chinese dining table. From the smooth and tender tofu pudding found on streets and lanes to the delicate soft tofu served at the home dining table, and then to the firm old tofu suitable for frying, stir-frying, stewing, and deep-frying, these various forms of tofu delicacies all originate from the same magical transformation. This paper examines the physical and chemical mechanisms underlying the remarkable transformation from soybeans to tofu, using firm tofu, soft tofu, and douhua (tofu pudding) as analytical entry points. Soybean milk constitutes a protein colloidal system, whose stability is maintained by electrostatic repulsion between charged colloidal particles and the protective hydration membrane surrounding them. The bittern curdling process, traditionally known as “brining”, is fundamentally an electrolyte-induced colloidal coagulation reaction. By precisely modulating the type and concentration of coagulants, we can systematically engineer a diverse spectrum of textural properties, ranging from the delicate consistency of douhua to the resilient firmness of laodoufu. This study elucidates the scientific principles embedded in traditional tofu production, revealing the intricate interplay between physical chemistry and everyday culinary practice, and also demonstrating our understanding and appreciation of cultural heritage.

Key words: Tofu, Bittern curdling, Colloidal system, Coagulation, Coagulants