氮中心自由基反应制备N―N偶联化合物

doi:10.12461/PKU.DXHX202404131

University Chemistry ›› 2025, Vol. 40 ›› Issue (1): 318-323.doi: 10.12461/PKU.DXHX202404131

Special Issue:

• Chemistry Laboratory • Previous Articles Next Articles

Preparation of N―N Coupling Compounds via Nitrogen-Centered Radical Reaction

Yuji Liu, Yuntian Zhang, Xu Jia, Zhiwei Zeng, Shupeng Zhang, Wei Dong, Yongxing Tang

School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China

Received:2024-04-22 Accepted:2024-06-25 Published:2025-01-06
Contact: Yongxing Tang E-mail:yongxing@njust.edu.cn

Abstract

Abstract: This study presents a nitrogen-centered radical reaction designed for undergraduate experimental teaching. By performing the same experiment under three different conditions, students become more familiar with the experimental procedures while deepening their understanding of the characteristics of radical reactions. The experiment is characterized by its simplicity, high efficiency, and reproducibility. Additionally, it incorporates elements of curriculum ideology and politics, such as energy conservation, emission reduction, and green chemistry, thereby fostering students’ scientific research and innovation skills. This reaction is well-suited for promotion as an undergraduate teaching experiment.

Key words: Radical reaction, Green chemistry, Pyrazole, Undergraduate experimental teaching

Yuji Liu, Yuntian Zhang, Xu Jia, Zhiwei Zeng, Shupeng Zhang, Wei Dong, Yongxing Tang. Preparation of N―N Coupling Compounds via Nitrogen-Centered Radical Reaction[J].University Chemistry, 2025, 40(1): 318-323.

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Preparation of N―N Coupling Compounds via Nitrogen-Centered Radical Reaction

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