框架材料色谱固定相及手性分离

doi:10.12461/PKU.DXHX202405174

Abstract

Abstract: Chirality plays an important role in fields such as biology, pharmacology and chemical reactions. In practical applications, only one specific configuration of chiral materials typically exhibits the desired effects, making chiral separation essential. The framework materials, with their diverse structures and ease of modification, are highly effective as chromatographic stationary phases for the efficient separation of chiral substances. This paper reviews the latest research on framework material stationary phases for chiral separations and discusses the challenges and application prospects of framework material stationary phases.

Key words: Metal-organic framework materials, Covalent organic frameworks, Hydrogen-bonded organic frameworks, Chiral separations for chromatography

Qiuting Zhang, Fan Wu, Jin Liu, Zian Lin. Chromatographic Stationary Phase and Chiral Separation Using Frame Materials[J].University Chemistry, 2025, 40(4): 291-298.

References

[1] Rikken, G. L.; Raupach, E. Nature 2000, 405, 932.
[2] Sun, Z. F.; Hou, J. J.; Li, L. S.; Tang, Z. Y. Coord. Chem. Rev. 2020, 425, 213481.
[3] Crosby, J. Tetrahedron 1991, 22.
[4] 王红磊, 许坤. 化工设计通讯, 2020, 46, 215.
[5] Sui, J.; Wang, N.; Wang, J.; Huang, X.; Wang, T.; Zhou, L.; Hao, H. Chem. Sci. 2023, 14, 11955.
[6] Zhong, H.; Deng, J. Polym. Rev. 2022, 62, 826.
[7] Li, X. F.; Zhu, Q. L. EnergyChem 2020, 2.
[8] Mínguez, E. G.; Coronado, E. Chem. Soc. Rev. 2018, 47, 533.
[9] Krause, S.; Bon, V.; Senkovska, I.; Stoeck, U.; Wallacher, D.; Többens, D. M.; Zander, S.; Pillai, R. S.; Maurin, G.; Coudert, F.-X.; et al. Nature 2016, 532, 348.
[10] Zhou, W. X.; Tang, Y. J.; Zhang, X. Y.; Zhang, S. T.; Xue, H. G.; Pang, H. Coord. Chem. Rev. 2023, 477, 214949.
[11] Ezuhara, T.; Endo, K.; Aoyama, Y. J. Am. Chem. Soc. 1999, 121, 3279.
[12] Corella-Ochoa, M. N.; Tapia, J. B.; Rubin, H. N.; Lillo, V.; González-Cobos, J.; Núñez-Rico, J. L.; Balestra, S. R. G.; Almora-Barrios, N.; Lledós, M.; Güell-Bara, A.; et al. J. Am. Chem. Soc. 2019, 141, 14306.
[13] Jiang, H.; Yang, K. W.; Zhao, X. X.; Zhang, W. Q.; Liu, Y.; Jiang, J. W.; Cui, Y. J. Am. Chem. Soc. 2021, 143, 390.
[14] Yu, Y. Y.; Xu, N. Y.; Zhang, J. H.; Wang, B. J.; Xie, S. M.; Yuan, L. M. ACS Appl. Mater. Interfaces 2020, 12, 16903.
[15] Ma, X.; Guo, Y.; Zhang, L.; Wang, K. X.; Yu, A. J.; Zhang, S. S.; Ouyang, G. F. Talanta 2022, 239, 123143.
[16] Kou, W. T.; Yang, C. X.; Yan, X. P. J. Mater. Chem. A 2018, 6, 17861.
[17] Fei, Z. X.; Zhang, M.; Zhang, J. H.; Yuan, L. M. Anal. Chim. Acta 2014, 830, 49.
[18] Li, Z. T.; Mao, Z. K.; Zhou, W.; Chen, Z. L. Talanta 2020, 218, 121160.
[19] Suttipat, D.; Butcha, S.; Assavapanumat, S.; Maihom, T.; Gupta, B.; Perro, A.; Sojic, N.; Kuhn, A.; Wattanakit, C. ACS Appl. Mater. Interfaces 2020, 12, 36548.
[20] Sun, X. D.; Niu, B.; Zhang, Q.; Chen, Q. J. Pharm. Anal. 2022, 12, 509.
[21] Xu, H.; Chen, X.; Gao, J.; Lin, J. B.; Addicoat, M.; Irle, S.; Jiang, D. L. Chem. Commun. 2014, 50, 1292.
[22] Han, X.; Huang, J. J.; Yuan, C.; Liu, Y.; Cui, Y. J. Am. Chem. Soc. 2018, 140, 892.
[23] Zhang, S. N.; Zheng, Y. L.; An, H. D.; Aguila, B.; Yang, C. X.; Dong, Y. Y.; Xie, W.; Cheng, P.; Zhang, Z. J.; Chen, Y.; et al. Angew. Chem., Int. Ed. 2018, 57, 16754.
[24] Xu, N. Y.; Guo, P.; Chen, J. K.; Zhang, J. H.; Wang, B. J.; Xie, S. M.; Yuan, L. M. Talanta 2021, 235, 122754.
[25] Wan, M. J.; Zheng, Y. C.; Dai, X. M.; Yang, H. L.; Zhou, J. Q.; Ou, J.; Yang, Y. X.; Liao, M. F.; Xia, Z. N.; Wang, L. J. Chem. Mater. 2023, 35, 609.
[26] Chen, Y. L.; Huang, S. M.; Xia, L.; Hu, Y. L.; Li, G. K. Anal. Chem. 2024, 96, 1380.
[27] Tang, B.; Wang, W.; Hou, H. P.; Liu, Y. Q.; Liu, Z. K.; Geng, L. N.; Sun, L. Q.; Luo, A. Q. Chin. Chem. Lett. 2022, 33, 898.
[28] Yuan, C.; Jia, W. Y.; Yu, Z. Y.; Li, Y. N.; Zi, M.; Yuan, L. M.; Cui, Y. J. Am. Chem. Soc. 2022, 144, 891.
[29] Yuan, C.; Wang, Z.; Xiong, W. Q.; Huang, Z. F.; Lai, Y. L.; Fu, S. G.; Dong, J. Q.; Duan, A. H.; Hou, X. D.; Yuan, L. M.; et al. J. Am. Chem. Soc. 2023, 145, 18956.
[30] Song, Q. Y.; Yang, J.; Zheng, K. N.; Zhang, T.; Yuan, C.; Yuan, L. M.; Hou, X. D. J. Am. Chem. Soc. 2024, 146, 7594.
[31] Wang, Y. Y.; Zhuo, S. Q.; Hou, J. W.; Li, W.; Ji, Y. B. ACS Appl. Mater. Interfaces 2019, 11, 48363.
[32] Wang, W.; Zhang, Y. K.; Tang, B.; Hou, H. P.; Tang, S. S.; Luo, A. Q. J. Chromatogr. A 2022, 1675.

Chromatographic Stationary Phase and Chiral Separation Using Frame Materials

PDF

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 6

Metrics

Recommended 0

[1]	Yueshuai Xu, Wei Liu, Xudong Chen, Zhikun Zheng. Experimental Teaching Design for the Preparation of Covalent Organic Framework Single Crystals in the Aqueous Phase [J]. University Chemistry, 2025, 40(6): 256-265.
[2]	Shengbiao Zheng, Liang Li, Nini Zhang, Ruimin Bao, Ruizhang Hu, Jing Tang. Metal-Organic Framework-Derived Materials Modified Electrode for Electrochemical Sensing of Tert-Butylhydroquinone: A Recommended Comprehensive Chemistry Experiment for Translating Research Results [J]. University Chemistry, 2024, 39(7): 345-353.
[3]	Fengwei Huang, Fulin Zhang, Yuexin Wang, Xianjun Lang. Cooperative Photocatalysis of a Semiconductor with a Persistent Radical TEMPO for Selective Oxidation Reactions [J]. University Chemistry, 2024, 39(12): 156-163.
[4]	Fan Wu, Wenchang Tian, Jin Liu, Qiuting Zhang, YanHui Zhong, Zian Lin. Core-Shell Structured Covalent Organic Framework-Coated Silica Microspheres as Mixed-Mode Stationary Phase for High Performance Liquid Chromatography [J]. University Chemistry, 2024, 39(11): 319-326.
[5]	Xiaohan Wang, Dongxiao Cao, Wei Li, Yan Chen, Anna Tang, Deming Kong. Synthesis and Application of Morphology Controllable Covalent Organic Frameworks [J]. University Chemistry, 2023, 38(5): 110-118.
[6]	Shichao Liu, Yaning Li, Yuxuan Zhan, Xiaohong Wang, Xiaoqin Zou. Design and Exploration of Synthesis and Oxidative Desulfurization Study of Polyoxometalate-Based Covalent Organic Framework in Experimental Teaching [J]. University Chemistry, 2022, 37(5): 2110079-.