几种光谱选择规律的证明与阐释

doi:10.12461/PKU.DXHX202408063

Abstract

Abstract: This study clarifies several ambiguities regarding the selection rules of atomic spectra found in structural chemistry textbooks, based on the fundamental formula of dipole matrix elements. It discusses the specific expressions for the spectroscopy of diatomic molecular rotation and vibration, as well as the infrared and Raman spectra of polyatomic molecules, ultraviolet-visible electronic spectroscopy, and circular dichroism spectroscopy. Relevant equivalence criteria are also provided. Additionally, the meanings and rationality of various spectroscopic selection rules are elucidated.

Key words: Electric dipole, Polarized dipole, Atomic spectroscopy, Molecular spectroscopy, Spectroscopic selection rules

Wenliang Wang, Weina Wang, Lixia Feng, Nan Wei, Sufan Wang, Tian Sheng, Tao Zhou. Proof and Interpretation of Severe Spectroscopic Selection Rules[J].University Chemistry, 2025, 40(3): 415-424.

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Proof and Interpretation of Severe Spectroscopic Selection Rules

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