Wilhelmy吊片法测定磷脂溶液的表面张力等温线

doi:10.3866/PKU.DXHX202201014

Abstract

Abstract:

The determination of surface tension isotherm of surfactants is an important experiment of college physical chemistry laboratory. With the wide application of surfactants and the development of scientific instruments, it is necessary to update the experimental system of classical surface tension isotherm measurements. Herein, the surface tension isotherm of distearoyl phosphatidylcholine (DSPC) and dipalmitoyl phosphatidylcholine (DPPC) were determined by interfacial tensiometer, and the important parameters such as surface excess and cross-sectional area of molecules were calculated. An extended experiment was also suggested so as to promote the students' comprehensive knowledge and cultivate the students' ability to analyze and solve problems.

Key words: Phospholipid, Surface tension isotherm, Laboratory teaching

Yuanfei Li, Xunfang Yang, Guiling Wang, Ying Guo, Xu Wang, Xinru Li, Yanxia Zhou, Ying Xie. Determination of Surface Tension Isotherm of Phospholipid Solution Using Wilhelmy Method[J].University Chemistry, 2023, 38(1): 155-160.

Figures/Tables 5

References 9

1	Bulbake, U.; Doppalapudi, S.; Kommineni, N.; Khan, W.Pharmaceutics2017,9(2),12.
2	Mizushima, Y.; Yanagawa, A.; Hoshi, K.J. Pharm. Pharmacol.1983,35(10),666.
3	Reddy, B. P. K.; Yadav, H. K. S.; Nagesha, D. K.; Raizaday, A.; Karim, A.J. Nanosci. Nanotechnol.2015,15(6),4009. doi: 10.1166/jnn.2015.9713
4	Tenchov, R.; Bird, R.; Curtze, A. E.; Zhou, Q.ACS Nano2021,15(11),16982. doi: 10.1021/acsnano.1c04996
5	义光, 杜丽娜, 陈昱, 凌沛学纳米技术在药物递送中的应用,北京:化学工业出版社,2015,167-168.
6	周亭, 杨世超, 张志庆, 张国栋, 王芳珠, 张予辉, 王芳, 王秀凤实验技术与管理,2018,35(1),53.
7	Kawanishi, T.; Seimiya, T.; Sasaki, T.J. Colloid Interface Sci.1970,32(4),622. doi: 10.1016/0021-9797(70)90154-2
8	李武宏, 汪继红, 陈纪岳, 林玉龙, 徐璐, 崔黎丽, 谢英物理化学实验指导双语教材,第2版北京:民卫生出版社,2011,107-110.
9	Chaban, V.Chem. Phys. Lett.2014,616,25.

样品	m_max/μg	Γ_m/(mol∙m⁻²)	A/m²
DSPC	8.38	3.75 × 10⁻⁶	4.43 × 10⁻¹⁹
DPPC	13.53	6.53 × 10⁻⁶	2.54 × 10⁻¹⁹

[1]	Yifan Xie, Liyun Yao, Ruolin Yang, Yuxing Cai, Yujie Jin, Ning Li. Experimental Design for HPLC Determination of Vitamin B₂ in Tablets via UVD-FLD Connected in Series [J]. University Chemistry, 2023, 38(9): 196-201.
[2]	Hanming Yang, Yan Zhang. Teaching Model and Practice of Inorganic Chemistry Laboratory Based on Cloud Desktop Platform [J]. University Chemistry, 2023, 38(8): 77-84.
[3]	Yiru Wang, Chunyan Zhang, Rui Pan, Zhenling Xu, Chanzi Ruan, Yinyun Lü, Jing Yang, Zhiqiang Dong, Yuhua Weng, Shunliu Deng, Yanping Ren. Exploration and Practice of Ideological and Political Education Elements in Laboratory Teaching Process: An Example for Preparation of N₂ and Mg₃N₂ [J]. University Chemistry, 2023, 38(5): 241-248.
[4]	Qilin Wang, Minghao Wang, Jixiang Xu, Junhua Liu. A Cleavage-Recombination Strategy of P—C(sp²) Bond to Assemble New Organic Phosphine [J]. University Chemistry, 2023, 38(4): 237-242.
[5]	Lan Huang, Wenyun Hu, Yunjun Mei. Reform and Practice of Environmental Chemistry Laboratory Teaching under the Background of Emerging Engineering Education [J]. University Chemistry, 2023, 38(3): 70-74.
[6]	Wei Wang, Lijun Dong, Dongyu Lv, Yong Huang, Jiang He. Construction and Practice of Inorganic & Analytical Chemistry Laboratory Course System Guided by the Cultivation of Innovative Talents [J]. University Chemistry, 2023, 38(2): 90-97.
[7]	Haibo Lei, Yanling Xu, Jian Ren, Wen Liu. Curriculum Construction of "Biomass Functional Material Comprehensive Laboratory" under the Background of New Agricultural Science [J]. University Chemistry, 2022, 37(8): 2108072-.
[8]	Jun Xuan, Weiwei Jin, Lei Li, Xiao Lian, Qiong Zhang, Chenjiang Liu. Application of Photochemical Synthesis of Nitrone under Continuous Flow in Undergraduate Laboratory Teaching [J]. University Chemistry, 2022, 37(7): 2109049-.
[9]	Bing Li, Xinxin Zhao, Wujiong Xia, Yunchen Du, Xijiang Han. Synthesis and Characterization of 1-Methyl-2-phenylindolin Induced by UV light: A Comprehensive Organic Micro Chemistry Experiment Converted from NSFC Research [J]. University Chemistry, 2022, 37(7): 2109039-.
[10]	Qianqian Zhu, Wen Wang. Exploration of Comprehensive Chemistry Laboratory (Ⅰ) Teaching Reform Guided by the Aim of Training Talents in Chemistry [J]. University Chemistry, 2022, 37(7): 2111035-.
[11]	Yinyi Liu, Zishan Su, Bixian Chen, Xin Deng, Shuru Tang, Shuman Lin, Haoyuan Xie, Xiaojun Liu, Wenting Liu, Weiqin Xu. Control the Morphology of Cu-MOF through Microemulsion Method as a Laboratory Teaching Case [J]. University Chemistry, 2022, 37(7): 2110071-.
[12]	Wanqun Zhang, Pingping Zhu, Wei Shao, Wanqun Hu. Construction and Teaching Practice on Virtual Simulation Experiment of in situ Variable temperature X-ray Diffraction [J]. University Chemistry, 2022, 37(2): 2109094-.
[13]	Yanyan Wang, Lingxiang Gao, Weiqiang Zhang, Quan Gu, Yajun Jian, Ziwei Gao. Integrating Green Chemistry into Teaching Laboratories: A Teaching Research on Green Suzuki-Miyaura Cross-Coupling Reaction [J]. University Chemistry, 2022, 37(12): 2112020-0.
[14]	Yingzhe Ni, Ziheng Zhang, Ran Hu, Fu Pi, Yuchen Gao, Qiue Cao, Chuanhua Zhou. ICP-AES Determination of Metal Ions in the Leaching Solution of Stainless Steel Thermos Cups [J]. University Chemistry, 2022, 37(12): 2112082-0.
[15]	Ya Wu, Rongmiao Fang, Dan Xue, Wenzhen Wang, Yefei Nan, Biyun Su, Jun Shi. Exploration and Practice of Chemistry Laboratory Skill Competition in Collaboration with Traditional Laboratory Teaching [J]. University Chemistry, 2022, 37(12): 2111083-0.

Determination of Surface Tension Isotherm of Phospholipid Solution Using Wilhelmy Method

RichHTML

PDF

Like

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 5

References 9

Related Articles 15

Metrics

Recommended 0