光电化学在有机合成中的应用

doi:10.3866/PKU.DXHX202202021

Abstract

Abstract:

In recent years, photoelectrochemistry has attracted more and more attention as an efficient method of organic synthesis. A combination of the amazing performance of photochemical catalysis and the anti-thermodynamic properties of electrochemical catalysis has greatly simplified several organic syntheses. In this paper, we introduce typical photoelectrochemical reactions, summarize several catalysts widely applied in photoelectrochemistry, and propose a perspective for further applications of photoelectrochemistry.

Key words: Photoelectrochemistry, Organic synthesis, Photo-sensitive dye

Haoran Cai, Xiayi Yao, Yuchao Cao, Zepeng Lu, Jiang Bian. Applications of Photoelectrochemistry in Organic Synthesis[J].University Chemistry, 2023, 38(1): 129-140.

Figures/Tables 16

References 44

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电化学操作方法	产率(转化率)
电化学操作方法	24b	25b
Ⅰ ^(a)	52% (84%)	~0 (100%)
Ⅱ ^(b)	86% (100%)	< 10% (100%)
Ⅲ ^(c)	71% (85%)	< 10% (100%)

基态	Red/Ox ^[a]	I_max ^[b]/nm	E_1/2 ^[c]/V vs. SCE
DCA ^[40]	Red	450, 480, 510	−0.82 → −3.2
PTZ ^[40]	Ox	514, 772	+0.70 → +2.9
TAC⁺ ^[25]	Ox	450, 500, 598	+1.26 → +3.3
RFT ^[27]	Ox	440	+1.67
Mes-Acr⁺ ^[41]	Ox	359, 422	+2.06
4CzIPN ^[42]	Ox	539	+1.43
DDQ ^[43]	Ox	465	+3.18

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Applications of Photoelectrochemistry in Organic Synthesis

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