在碱金属/液氨作用下两类还原反应的机理探讨

doi:10.3866/pku.DXHX20150458

Abstract

Abstract:

Alkali metal in liquid ammonia is widely applied in organic synthetic chemistry as a strong reducible reagent. Reduction reactions with alkali metal such as converting alkynes to olefins and Birch reactions are detailed described before. Here, we discuss its mechanisms further according to recent published literatures.

Key words: Organic chemistry, Alkali metal, Alkynes to olefins, Birch reaction

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Dai Yazhong, Pei Jian. Mechanisms of Two Reduction Reactions under the Condition of Alkali Metal in Liquid Ammonia[J].University Chemistry, 2015, 30(4): 58-62.

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URL: https://www.dxhx.pku.edu.cn/EN/10.3866/pku.DXHX20150458

https://www.dxhx.pku.edu.cn/EN/Y2015/V30/I4/58

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Mechanisms of Two Reduction Reactions under the Condition of Alkali Metal in Liquid Ammonia

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