金属催化下环丙烯酮参与的β-碳消除反应介绍

doi:10.3866/PKU.DXHX202401060

University Chemistry ›› 2024, Vol. 39 ›› Issue (8): 169-173.doi: 10.3866/PKU.DXHX202401060

• Survey of Chemistry • Previous Articles Next Articles

Introduction to Metal-Catalyzed β-Carbon Elimination Reaction of Cyclopropenones

Guojie Xu¹, Fang Yu², Yunxia Wang¹, Meng Sun¹

1. College of Chemistry and Materials Science, Northwest University, Xi'an 710127, China;
2. Xi'an Gaoxin No. 1 High School, Xi'an 710075, China

Received:2024-01-22 Revised:2024-04-25 Published:2024-08-08
Contact: Meng Sun E-mail:sunmeng@nwu.edu.cn

Abstract

Abstract: Cyclopropenones, possessing Hückel aromaticity, are three-membered cyclic compounds that serve as ideal substrates for C―C bond activation. This paper provides a comprehensive summary of the organic chemical reactions involving cyclopropenones through the β-carbon elimination pathway, thus offering valuable references for the study of transition metal-catalyzed C―C bond activation reactions and the transformation applications of cyclopropenones.

Key words: Cyclopropenones, C―C bond activation, β-Carbon elimination, Teaching method

Guojie Xu, Fang Yu, Yunxia Wang, Meng Sun. Introduction to Metal-Catalyzed β-Carbon Elimination Reaction of Cyclopropenones[J].University Chemistry, 2024, 39(8): 169-173.

[1]	Shangwen Luo, Jianguo Fang, Yanlong Yang, Shihui Dong. Practice and Exploration of Bilingual Teaching in the Chemical Biology Course [J]. University Chemistry, 2025, 40(8): 124-129.
[2]	Liqiang Huang, Peng Lin. Addressing Pedagogical Challenges in Instrument Analysis Experiment Course through Numerical Graph Analysis [J]. University Chemistry, 2025, 40(6): 353-359.
[3]	Dongdong Yao, JunweiGu, Yi Yan, Junliang Zhang, Yaping Zheng. Teaching Phase Separation Mechanism in Polymer Blends Using Process Representation Teaching Method: A Teaching Design for Challenging Theoretical Concepts in “Polymer Structure and Properties” Course [J]. University Chemistry, 2025, 40(4): 131-137.
[4]	Renxiu Zhang, Xin Zhao, Yunfei Zhang. Application of Electrochemical Synthesis in the Teaching of Organic Chemistry [J]. University Chemistry, 2025, 40(4): 174-180.
[5]	Le Yang, Chuanxiao Yang, Yifei Zhao, Yaming Yu, Jingling Chen, Wei Xie. Exploration and Practice of Preparatory Chemistry Teaching for Overseas Students in China [J]. University Chemistry, 2025, 40(3): 259-268.
[6]	Zhentong Zhu, Peiyao Du, Chaoqin Zeng, Rui Zhou, Xiaoyan He, Bingzhang Lu, Xiaoquan Lu. Discussion on Teaching Methods for Bilingual Courses in Instrumental Analysis for Chemistry Majors [J]. University Chemistry, 2025, 40(10): 39-45.
[7]	Fan Yang, Yanhong Bai, Pin Gao, Xinhua Duan, Yunchuan Xie. Exploration and Practice of Teaching Reform in Polymer Chemistry Experiment Course [J]. University Chemistry, 2025, 40(10): 63-71.
[8]	Peifeng Su, Xin Lu. Development of Undergraduate Quantum Mechanics Module in Chemistry Department under the “Double First Class” Initiative [J]. University Chemistry, 2024, 39(8): 99-103.
[9]	Guoxian Zhu, Jing Chen, Rongkai Pan. Enhancing the Teaching Quality of Atomic Structure: Insights and Strategies [J]. University Chemistry, 2024, 39(3): 376-383.
[10]	Yuqiao Zhou, Weidi Cao, Shunxi Dong, Lili Lin, Xiaohua Liu. Study on the Teaching Reformation of Practical X-ray Crystallography [J]. University Chemistry, 2024, 39(3): 23-28.
[11]	Sheng Zhang, Mingyu Wang, Xiaohong Wang, Jiancheng Feng. Multidimensional Teaching Design and Ideological and Political Exploration of Analytical Chemistry Experiment under the Complete Credit System [J]. University Chemistry, 2024, 39(2): 189-195.
[12]	Fangna Dai, Rongming Wang, Zhicheng Zhang. Reform and Practice of Case Teaching on “Laboratory Safety Management Standards and Training” [J]. University Chemistry, 2024, 39(10): 121-127.
[13]	Chi Zhang, Suqi Wu, An Liu, Wei Zhang, Xiao Wei. Application of Team-Based Learning Teaching Method in Inorganic Chemistry Course: the Design Case of Inorganic Chemistry Teaching in Chemistry “101 Plan” [J]. University Chemistry, 2024, 39(10): 89-95.
[14]	Xianfu Chen, Meng Zhang, Changsong Wang. Innovative Teaching Exploration for Heat Conduction Chapter of Chemical Engineering Transfer Course [J]. University Chemistry, 2024, 39(1): 314-319.
[15]	Chunmiao Bo, Guxia Wang. Integrating Modern Media, Innovative Teaching Approaches, and Ideological and Political Education in the "Emerging Engineering Education" of Analytical Chemistry Curriculum [J]. University Chemistry, 2024, 39(1): 29-37.

Introduction to Metal-Catalyzed β-Carbon Elimination Reaction of Cyclopropenones

PDF

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Recommended 0