几种经典有机反应的分子轨道描述

doi:10.3866/PKU.DXHX201510006

University Chemistry ›› 2016, Vol. 31 ›› Issue (8): 60-65.doi: 10.3866/PKU.DXHX201510006

• Survey of Chemistry • Previous Articles Next Articles

Molecular Orbital Description on Several Classical Organic Reactions

Wei XU,Jia-Xi XU*()

Department of Organic Chemistry, Faculty of Science, Beijing University of Chemical Technology, Beijing 100029, P. R. China

Published:2016-08-31
Contact: Jia-Xi XU E-mail:jxxu@buct.edu.cn

Abstract

Abstract:

It is very important to describe organic reaction processes with molecular orbitals, especially frontier orbitals, for correct and completely understanding of organic reaction mechanisms. Molecular orbital description can provide useful information on selectivity and stereochemistry of organic reactions. Molecular orbital descriptions on several classic organic reactions, including aliphatic and aromatic nucleophilic substitutions, electrophilic aromatic substitution, addition and elimination, are discussed.

Key words: Organic reaction, Molecular orbital, Nucleophilic substitution, Addition, Elimination

Wei XU,Jia-Xi XU. Molecular Orbital Description on Several Classical Organic Reactions[J].University Chemistry, 2016, 31(8): 60-65.

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Molecular Orbital Description on Several Classical Organic Reactions

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