MOF衍生的多孔碳材料制备及其电容性能研究——基于OBE理念设计一个综合化学实验

doi:10.12461/PKU.DXHX202405099

Abstract

Abstract: Grounded in the principles of Outcome-Based Education (OBE) and aligned with graduation requirements and course objectives, we designed a comprehensive experiment titled “Preparation of Porous Carbon Materials Derived from MOF and Their Capacitance Performance”. This experiment involves the synthesis of Zn-MOF-5 using a direct addition method under atmospheric pressure, followed by the preparation of layered porous carbon materials through processes such as carbonization and acid washing, which were then characterized. Finally, we investigated the electrochemical properties of these materials. Through this comprehensive experiment, students not only gain insights into the cutting-edge field of supercapacitors but also enhance their skills in material synthesis and characterization, instrument operation, and data analysis. This experience fosters their ability to integrate knowledge across disciplines, solve complex problems, stimulate innovative thinking, and develop teamwork and communication skills. Ultimately, this supports students in meeting the graduation requirements of advanced engineering education.

Key words: OBE concept, Comprehensive chemistry experiment, MOF, Porous carbon materials, Supercapacitor

Junxin Duan, Ao Yu, Quanhua Li, Deyu Qu, Dan Liu, Dongbing Cheng, Dongxue Wang, Xi Li. Preparation of Porous Carbon Materials Derived from MOF and Their Capacitance Performance: Design of a Comprehensive Chemistry Experiment Based on the OBE Concept[J].University Chemistry, 2025, 40(2): 297-305.

References

[1] 李永军, 王玉枝, 张晓兵, 范媛吉, 蔡炽, 陈淑云, 吴英鹏. 大学化学, 2021, 36 (5), 2008022.
[2] 李育佳, 贾叙东, 陈露洪, 朱成建. 大学化学, 2019, 34 (10), 14.
[3] 谢钢, 吴彪, 陈三平, 马向科, 赵志厚, 马佳妮, 谭青山, 赵晓霞. 大学化学, 2020, 35 (9), 41.
[4] Spady, W. D. Outcome-Based Education: Critical Issues and Answers; American Association of School Administrators: Arlington, TX, USA, 1994; pp. 4-26.
[5] 鞠志宇, 舒朋华, 谢智宇, 李公春. 化学教育, 2020, 41 (2), 71.
[6] 郭虹琦, 刘婷, 王德义, 苏柏方, 黄一川, 李振彪, 李红岩, 卢爱党. 化学教育, 2020, 41 (8), 67.
[7] Sardana, S.; Gupta, A.; Singh, K.; Maan, A. S.; Ohlan, A. J. Energy Storage 2022, 45, 103510.
[8] Wu, G.; Wu, X. J.; Zhu, X. L.; Xu, J. H.; Bao, N. Z. ACS Nano. 2022, 16 (7), 10130.
[9] Li, Z. J.; Guo, D. F.; Liu, Y. Y.; Wang, H. Y.; Wang, L. L. Chem. Eng. J. 2020, 397, 125418.
[10] Kumar, S.; Saeed, G.; Zhu, L.; Hui, K. N.; Kim, N. H.; Lee, J. H. Chem. Eng. J. 2021, 403, 126352.
[11] Zhou, J. W.; Wang, B. Chem. Soc. Rev. 2017, 46 (22), 6927.
[12] Kaye, S. S.; Dailly, A.; Yaghi, O. M.; Long, J. R. J. Am. Chem. Soc. 2007, 129, 14176.
[13] Tsao, C. S.; Yu, M. S.; Chung, T. Y.; Wu, H. C.; Wang, C. Y.; Chang, K. S.; Chent, H. L. J. Am. Chem. Soc. 2007, 129 (51), 15997.
[14] Liu, B.; Shioyama, H.; Akita, T.; Xu, Q. J. Am. Chem. Soc. 2008, 130 (16), 5390.
[15] Saha, D.; Deng, S. G.; Yang, Z. G. J. Porous Mater. 2009, 16, 141.
[16] Zhang, L.; Hu, Y. H. Appl. Surf. Sci. 2011, 257, 3392.
[17] Burgaz, E.; Erciyes, A.; Andac, M.; Andac, O. Inorg. Chim. Acta 2019, 485, 118.
[18] Hermes, S.; SchrÖder, F.; Amirjalayer, S.; Schmid, R.; Roland, A. J. Mater. Chem. 2006, 16, 2464.
[19] Phan, N. T. S.; Le, K. K.A.; Phan, T. D. Appl. Catal. A 2010, 382, 246.
[20] 孙红, 柳志刚, 陈敏. 大连交通大学学报, 2013, 34 (4), 102.
[21] Huang, L. M.; Wang, H. T.; Chen, J. X.; Wang, Z. B.; Sun, J. Y.; Zhao, D. Y.; Yan, Y. S. Microporous Mesoporous Mat. 2003, 58 (2),105.
[22] Van Vleet, M. J.; Weng, T. T.; Li, X. Y.; Schmidt, J. R. Chem. Rev. 2018, 118 (7), 3681.
[23] Wang, H. G.; Wu, Z.; Meng, F. L.; Ma, D. L.; Huang, X. L.; Wang, L. M.; Zhang, X. B. ChemSusChem 2013, 6 (1), 56.
[24] 江兰兰, 王先友, 张小艳, 吴昊, 吴春. 电源技术, 2014, 38 (8), 1497.
[25] 黄思赟, 李帅, 丁万, 王一. 化学试剂, 2022, 44 (5), 691.
[26] 王丕涛, 武丽丽, 陈鑫国, 张建强, 雒和明. 兰州理工大学学报, 2022, 48 (5), 21.

Preparation of Porous Carbon Materials Derived from MOF and Their Capacitance Performance: Design of a Comprehensive Chemistry Experiment Based on the OBE Concept

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