金属硼化物的制备、性质与应用研究进展

doi:10.3866/PKU.DXHX202302053

Abstract

Abstract:

The amount of charge transfer between metal and boron atoms determines the bonding mode, bonding strength and characteristics of chemical bonds in metal borides (MBs). The preparation, crystal structures and applications of MBs have been a hot topic in the field of chemistry and materials. In view of the extensive application prospect and the limited introduction of MBs in inorganic chemistry textbooks at domestic and abroad, in this work, combined with the references and the latest research results, we focus on the structure, properties, preparation and applications of alkali/alkaline earth metal borides, transition metal borides and rare earth metal borides. This work expands the in-depth introduction of MBs in teaching, helps improve students' knowledge horizons, and reflects the role of scientific research in promoting the reform of undergraduate teaching content.

Key words: Metal boride, Structure, Property, Preparation, Application

Xiaojun Zhao, Shengli Gao, Zhihong Liu. Progress in Preparation, Properties and Applications of Metal Borides[J].University Chemistry, 2023, 38(11): 95-105.

Figures/Tables 7

References 68

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化学式	晶体结构	晶系	硼结构	化合物种类
M₂B		Tetragonal	单硼原子、硼原子对	M是3d中部至后部(从Mn到Ni)低氧化态金属中的某一个
		Orthorhombic
MB		Tetragonal Orthorhombic	链式、双链式	MB (M = Ni、Co、Fe、Mo、Mn、Ti等)
MB₂		Hexagonal	二维硼网	包括Mg、Al、前d区金属(例如从Sc到Mn的第四周期元素)和U、Ti₂B₅和W₂B₅
MB₄		Tetragonal	三维硼网	钙、钇、镧系和锕系金属的四硼化物
MB₆		Cubic (CsCl型)	三维硼网	碱金属、碱土金属、镧系和锕系金属的六硼化物
MB₁₂		Cubic (NaCl型)	三维硼网	(MB₁₂ = Sc、Zr、Hf、Y、Lu)

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