有机电化学与化学教学

doi:10.12461/PKU.DXHX202407027

Abstract

Abstract: Organic electrochemistry has been recognized as one of the top ten emerging technologies in chemistry by International Union of Pure and Applied Chemistry (IUPAC) in 2023. As a crucial branch of fundamental chemistry in undergraduate education, electrochemistry is primarily addressed in the context of inorganic chemistry (specifically redox reactions) and physical chemistry (in relation to electrolyte solutions). However, references to organic electrochemistry in undergraduate curricula are notably scarce. This article presents recent research trends in organic electrochemistry and discusses considerations for incorporating organic electrochemistry into undergraduate chemistry teaching.

Key words: Organic electrochemistry, Electrochemical synthesis, Redox reaction, Undergraduate teaching

Hong Yan, Wenfeng Wang, Keyin Ye, Yaofeng Yuan. Organic Electrochemistry and Its Integration into Chemistry Teaching[J].University Chemistry, 2025, 40(5): 301-310.

References

[1] Yang, Q.-L.; Li, Y.-Q.; Ma, C.; Fang, P.; Zhang, X.-J.; Mei, T.-S. J. Am. Chem. Soc. 2017, 139, 3293.
[2] Li, P.; Zhu, Z.; Guo, C.; Kou, G.; Wang, S.; Xie, P.; Ma, D.; Feng, T.; Wang, Y.; Qiu, Y. Nat. Catal. 2024, 7, 412.
[3] Yan, H.; Hou, Z.-W.; Xu, H.-C. Angew. Chem. Int. Ed. 2019, 58, 4592.
[4] Shen, T.; Li, Y.-L.; Ye, K.-Y.; Lambert, T. H. Nature 2023, 614, 275.
[5] Hu, Q.; Wei, B.; Wang, M.; Liu, M.; Chen, X.-W.; Ran, C.-K.; Wang, G.; Chen, Z.; Li, H.; Song, J.; et al. J. Am. Chem. Soc. 2024, 146, 14864.
[6] Zhang, P.; Sheng, X.; Chen, X.; Fang, Z.; Jiang, J.; Wang, M.; Li, F.; Fan, L.; Ren, Y.; Zhang, B.; et al. Angew. Chem. Int. Ed. 2019, 58, 9155.
[7] Zou, L.; Sun, R.; Tao, Y.; Wang, X.; Zheng, X.; Lu, Q. Nat. Commun. 2024, 15, 5245.
[8] Yan, H.; Song, J.; Zhu, S.; Xu, H.-C. CCS Chem. 2021, 3, 317.
[9] Chen, P.-Y.; Huang, C.; Jie, L.-H.; Guo, B.; Zhu, S.; Xu, H.-C. J. Am. Chem. Soc. 2024, 146, 7178.
[10] Chen, Y.; He, Y.; Gao, Y.; Xue, J.; Qu, W.; Xuan, J.; Mo, Y. Science 2024, 384, 670.
[11] Hioki, Y.; Costantini, M.; Griffin, J.; Harper, K. C.; Merini, M. P.; Nissl, B.; Kawamata, Y.; Baran, P. S. Science 2023, 380, 81.
[12] Zeng, L.; Jiao, Y.; Yan, W.; Wu, Y.; Wang, S.; Wang, P.; Wang, D.; Yang, Q.; Wang, J.; Zhang, H.; et al. Nat. Synth. 2023, 2, 172.
[13] Vollhardt, P.; Schore, N. E. Organic Chemistry Structure and Function, 7th ed.; W. H. Freeman and Company: New York, NY, USA, 2014; p. 1088.
[14] 郑录, 罗兰. 大学化学, 1998, 3 (2), 8.
[15] 蔡浩然, 姚夏奕, 曹宇超, 陆泽鹏, 卞江. 大学化学, 2023, 38 (1), 129.
[16] 郭维斯, 王书文, 李明. 大学化学, 2023, 38 (5), 157.
[17] 胡新伟, 阮志雄. 大学化学, 2023, 38 (9), 263.
[18] 杨甫林, 李家欣, 冯立纲. 大学化学, 2023, 38 (9), 242.
[19] 杨鹰, 周湘林, 谭勇棋, 侯勃宇, 刘佳惠, 王智林, 崔红波, 刘哲, 李聪, 崔斌, 等. 大学化学, 2023, 38 (4), 160.
[20] 张震, 王世龙, 刘珊珊, 李文佐, 何涛, 李家柱. 大学化学, 2023, 38 (8), 128.
[21] 邹子燕, 孙承博, 刘春燕, 李晓驰, 冯鹏举. 大学化学, 2023, 38 (4), 336.
[22] Xiang, J.; Shang, M.; Kawamata, Y.; Lundberg, H.; Reisberg, S. H.; Chen, M.; Mykhailiuk, P.; Beutner, G.; Collins, M. R.; Davies, A.; et al. Nature 2019, 573, 398.
[23] 林彩霞, 施兆江, 余意, 鄢剑锋, 叶克印, 袁耀锋. 大学化学, 2024, 39 (2), 61.

Organic Electrochemistry and Its Integration into Chemistry Teaching

PDF

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Recommended 0

[1]	Fengxiao Wang, Zhiwei Miao, Yaofeng Yuan. Organophosphorus Chemistry and Its Integration in Teaching of Chemistry [J]. University Chemistry, 2025, 40(8): 158-168.
[2]	Zufeng Qiu, Jie Ouyang, Yiru Wang, Hengting Yang, Xin Liao, Chi Zhang, Xuanyao Jiang, Shunliu Deng, Zhiwei Lin. Comprehensive Instrument Analysis of “Blind Box” Samples: Analysis of Unknown Substances [J]. University Chemistry, 2025, 40(6): 296-302.
[3]	Meihong Luo, Hongyu Wang. Teaching Reform of Benzoin Oxidation Experiment in the Context of Green Pharmaceutical Chemistry [J]. University Chemistry, 2025, 40(5): 376-382.
[4]	Renxiu Zhang, Xin Zhao, Yunfei Zhang. Application of Electrochemical Synthesis in the Teaching of Organic Chemistry [J]. University Chemistry, 2025, 40(4): 174-180.
[5]	Jiajie Li, Xiaocong Ma, Jufang Zheng, Qiang Wan, Xiaoshun Zhou, Yahao Wang. Recent Advances in In-Situ Raman Spectroscopy for Investigating Electrocatalytic Organic Reaction Mechanisms [J]. University Chemistry, 2025, 40(4): 261-276.
[6]	Caixia Lin, Ting Liu, Zhaojiang Shi, Hong Yan, Keyin Ye, Yaofeng Yuan. Innovative Experiment of Electrochemical Dearomative Spirocyclization of N-Acyl Sulfonamides [J]. University Chemistry, 2025, 40(4): 359-366.
[7]	Ke Liu, Mingjing Deng, Jingbo Chang, Ailing Wang, Guoshuai Wu, Longyang Dian. Electrochemistry Mediated Direct Amination to Construct the Hemiaminal Ether Skeletons (HESs) [J]. University Chemistry, 2025, 40(2): 272-277.
[8]	Shuhui Li, Yujing Zhou, Haitao Tang. Overview of Organic Electrochemical Synthesis [J]. University Chemistry, 2025, 40(2): 210-215.
[9]	Yifei Cheng, Jiahui Yang, Wei Shao, Wanqun Zhang, Wanqun Hu, Weiwei Li, Kaiping Yang. Learning Goes Beyond the Written Word: Practical Insights from the “Leaf Electroplating” Popular Science Experiment [J]. University Chemistry, 2024, 39(9): 319-327.
[10]	Ji-Quan Liu, Huilin Guo, Ying Yang, Xiaohui Guo. Calculation and Discussion of Electrode Potentials in Redox Reactions of Water [J]. University Chemistry, 2024, 39(8): 351-358.
[11]	Yongpo Zhang, Xinfeng Li, Yafei Song, Mengyao Sun, Congcong Yin, Chunyan Gao, Jinzhong Zhao. Synthesis of Chlorine-Bridged Binuclear Cu(I) Complexes Based on Conjugation-Driven Cu(II) Oxidized Secondary Amines [J]. University Chemistry, 2024, 39(5): 44-51.
[12]	Li Jiang, Changzheng Chen, Yang Su, Hao Song, Yanmao Dong, Yan Yuan, Li Li. Electrochemical Synthesis of Polyaniline and Its Anticorrosive Application: Improvement and Innovative Design of the "Chemical Synthesis of Polyaniline" Experiment [J]. University Chemistry, 2024, 39(3): 336-344.
[13]	Caixia Lin, Zhaojiang Shi, Yi Yu, Jianfeng Yan, Keyin Ye, Yaofeng Yuan. Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment [J]. University Chemistry, 2024, 39(2): 61-66.
[14]	Balati Hasimujiang, Caifeng Hu, Yawen Huang, Mu Chen, Xinwei Hu, Zhixiong Ruan. Comprehensive Experimental Design for Solvent-Controlled Electrochemical Synthesis of Selenium-Containing Pyranone and Chalcone [J]. University Chemistry, 2024, 39(12): 273-283.
[15]	Jingpei Jia, Youai Qiu. Experimental Design for the Electrochemical Nucleophilic Aromatic Substitution Reaction [J]. University Chemistry, 2024, 39(12): 265-272.