生物质能源化学品乙酰丙酸酯

doi:10.3866/PKU.DXHX202004043

Abstract

Abstract:

As the emerging renewable energy, biomass energy is the fourth largest energy next to coal, oil and natural gas. Alkyl levulinates are high value-added products obtained from biomass resources, which are an important class of chemical intermediates and new energy chemicals. The application of alkyl levulinates is very broad and has potential commercial value. This article introduces the physicochemical properties and uses of levulinates, together with three synthetic methods and reaction mechanism for preparing alkyl levulinates using biomass resources as raw materials. Finally, the deficiencies of alkyl levulinates production and application is analyzed, and the development trend of the future development and utilization of alkyl levulinates is provided.

Key words: Biomass, Energy chemistry, Alkyl levulinates, Catalytic conversion

Wenguang Zhao, Jie Zhu, Jingxin Shi, Xianxiang Liu. Biomass-Based Energy Chemical: Alkyl Levulinates[J].University Chemistry, 2021, 36(4): 2004043.

Figures/Tables 8

References 29

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乙酰丙酸酯	分子式	分子量	密度/(g·mL^-1, at 25 ℃)	熔点/℃	沸点/℃	折光率(at 20 ℃)	闪点/℃
乙酰丙酸甲酯	C₆H₁₀O₃	130.14	1.051	-24	196	1.422	72
乙酰丙酸乙酯	C₇H₁₂O₃	144.17	1.016	-33	206	1.422	90
乙酰丙酸丙酯	C₈H₁₄O₃	158.19	0.981	N/A	218	1.421	88
乙酰丙酸异丙酯	C₈H₁₄O₃	158.19	0.984	N/A	209	1.442	N/A
乙酰丙酸正丁酯	C₉H₁₆O₃	172.22	0.974	N/A	238	1.427	197
乙酰丙酸异丁酯	C₉H₁₆O₃	172.22	0.967	N/A	228	1.425	N/A

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Biomass-Based Energy Chemical: Alkyl Levulinates

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