第33届江苏省化学竞赛选拔赛有机试题解析

doi:10.3866/PKU.DXHX202005042

Abstract

Abstract:

Organic-chemistry-related questions in the 33rd Jiangsu Province senior high school chemistry Olympiad selection contest are analyzed and elaborated upon in detail. To assist teaching, computational chemistry was utilized and served as a reference for instructors and participating students.

Key words: Chemistry Olympiad Competition, Question analyses, Organic chemistry, Computational chemistry, Knowledge extension

Yihan Tang, Jiawei Xu, Jiaxin Wang, Yuru Wang, Bing Xue, Zhihui Zhang. Analysis of Organic-Chemistry-Related Questions for the 33rd Jiangsu Chemistry Olympiad Selection Contest[J].University Chemistry, 2021, 36(4): 2005042.

Figures/Tables 18

References 22

1	贺麒霖; 米天雄; 孙桐; 杨中天; 余子迪; 柳晗宇. 大学化学, 2015, 30 (5), 69.
2	常泰维; 陈胤霖; 崔竞蒙; 董学洋; 柳晗宇; 鲁亮; 潘书廷; 孙泽昊. 大学化学, 2016, 31 (12), 90.
3	常泰维; 戴昱民; 方润亭; 李宇轩; 孙斯达; 孙泽昊; 王泽淳; 曾承禹; 张宇婷. 大学化学, 2018, 33 (1), 73.
4	柳晗宇. 大学化学, 2020, 35 (3), 134.
5	Zhao J. X. ; Méndez-Sánchez D. ; Ward J. M. ; Hailes H. C. J. Org. Chem. 2019, 84 (12), 7702. doi: 10.1021/acs.joc.9b00527
6	iBonD 2.0. [2020-06-11]. http://ibond.nankai.edu.cn
7	Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Scalmani, G.; Barone, V.; Petersson, G. A.; Nakatsuji, H.; et al. Gaussian 16, Revision C. 01; Gaussian, Inc. : Wallingford CT, USA, 2016.
8	Lu T. ; Chen F. W. J. Comput. Chem. 2012, 33 (5), 580. doi: 10.1002/jcc.22885
9	Humphrey W. ; Dalke A. ; Schulten K. J. Mol. Graph. 1996, 14 (1), 33. doi: 10.1016/0263-7855(96)00018-5
10	Li, J. J. Name Reactions: A Collection of Detailed Mechanisms and Synthetic Applications. 5th ed.; Springer: Cham, Switzerland, 2014; pp. 480, 56, 593.
11	邢其毅, 裴伟伟, 徐瑞秋, 裴坚. 基础有机化学. 第4版. 北京: 高等教育出版社, 2016: 459, 570, 483, 535, 53, 669, 498, 117, 762.
12	Malin L. ; Johan U. ; Hans E. ; Susanne W. ; Johan B. ; Marianne S. ; Martin A. H. ; Luna P. G. ; Annika W. E. ; Johan M. ; et al J. Med. Chem. 2019, 62 (9), 4325. doi: 10.1021/acs.jmedchem.8b02012
13	Edward O. ; Zhu X. Y. ; Etukala J. R. ; Bricker B. A. ; Ablordeppey S. Y. Bioorgan. Med. Chem. 201, 24 (55), 5730.
14	Teodozyj K. ; David E. G. ; Pramila B. ; Anwer B. ; Richard A. C. ; Andrew O. S. ; Jennifer B. B. ; Richard R. H. ; Keren I. H. ; Peter E. M. ; et al J. Med. Chem. 2000, 43 (17), 3322. doi: 10.1021/jm000180n
15	Kerns, J. K.; Yan, H. X.; Callahan, J. F.; Heightman, T. D.; Boehm, J. C.; Woodlrod, A. J. -A. Aryl-and heteroarylalkanoic acid derivatives as NRF2 regulators and their preparation. Int. Appl. WO2016203401A1, 2016.
16	卢天; 陈飞武. 物理化学学报, 2012, 28 (1), 1. doi: 10.3866/PKU.WHXB2012281
17	Reed A. E. ; Weinstock R. B. ; Weinhold F. J. Chem. Phys. 1985, 83 (2), 735.
18	Lu T. ; Chen F. W. J. Theor. Comput. Chem. 2012, 11 (1), 163. doi: 10.1142/S0219633612500113
19	Eric R. P. ; Donald J. H. J. Am. Chem. Soc. 1980, 102 (8), 2763. doi: 10.1021/ja00528a041
20	杨天翼; 张杰. 化学教育(中英文), 2018, 39 (13), 79.
21	Bentiss F. ; Lagrenee M. J. Heterocyclic Chem. 1999, 36 (4), 1029. doi: 10.1002/jhet.5570360433
22	Jakopin Z. ; Dolenc M. S. Curr. Org. Chem. 2008, 12 (10), 850. doi: 10.2174/138527208784911860

结构	NPA方法	ADCH方法
	0.50654	0.313845
	0.36088	0.169621

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Analysis of Organic-Chemistry-Related Questions for the 33rd Jiangsu Chemistry Olympiad Selection Contest

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