多孔碳包覆铜纳米颗粒的制备及性能表征——推荐一个化学综合实验

doi:10.3866/PKU.DXHX202206029

Abstract

Abstract:

Cu nanoparticles (NPs) supported on nitrogen-doped porous carbon (NPC) were synthesized by pyrolysis of Cu-metal organic frameworks (MOF) and characterized using scanning electron microscopy (SEM), X-ray diffraction (XRD), and infrared spectroscopy (IR) to investigate their morphology and composition. In addition, the catalytic performance for the hydrogenation of nitrobenzene was explored and the catalytic reaction conditions were optimized. The methodical experimental procedure was designed in a comprehensive manner to cultivate scientific thinking and enhance the overall analytical skills of students.

Key words: N-doped porous carbon, MOF-derived materials, Catalytic hydrogenation, Comprehensive experiment

Haoyuan Xie, Weiying Xiao, Shuru Tang, Xin Deng, Jing Tan, Zecheng Lv, Zuoyi Chen, Wenting Liu, Weiqin Xu. Preparation and Characterization of Cu Nanoparticles on Porous Carbon: A Recommended Comprehensive Chemistry Experiment[J].University Chemistry, 2023, 38(2): 227-232.

Figures/Tables 5

References 17

1	谢敏; 程世博; 吴卫兵; 黄驰; 龚淑玲. 实验技术与管理, 2014, 31 (11), 52. doi: 10.3969/j.issn.1002-4956.2014.11.015
2	何田; 尹守春; 李博. 大学化学, 2020, 35 (9), 126.
3	邱文达; 肖红兵. 实验技术与管理, 2021, 38 (5), 94.
4	Zhao X. ; Kong X. P. ; Wang F. L. ; Fang R. Q. ; Li Y. W. Angew. Chem. Int. Ed. 2021, 60, 10842. doi: 10.1002/anie.202016591
5	Yu H. J. ; Guo G. N. ; Ji L. ; Yang D. ; Hu J. H. ; Dong A. G. Nano Res. 2016, 9, 3757. doi: 10.1007/s12274-016-1246-z
6	Tian H. ; Liu X. Y. ; Dong L. B. ; Ren X. M. ; Liu H. ; Hurd P. C. A. ; Li Y. ; Wang G. X. ; Yang Q. H. ; Liu J. Adv. Sci. 2019, 6, 1900807. doi: 10.1002/advs.201900807
7	Budi C. S. ; Deka J. R. ; Hsu W. C. ; Saikia D. ; Chen K. T. ; Kao H. M. ; Yang Y. C. J. Hazard. Mater. 2021, 407, 124392. doi: 10.1016/j.jhazmat.2020.124392
8	Zhu J. ; Xu D. ; Ding L. J. ; Wang P. C. Chem. Eur. J. 2021, 27, 2707. doi: 10.1002/chem.202003640
9	Zhao R. ; Gao S. ; Wu Y. X. ; Liang Z. B. ; Zhang H. ; Xia W. ; Li S. ; Zhao Y. S. ; Zou R. Q. Chem. Eur. J. 2020, 26, 4001. doi: 10.1002/chem.201904280
10	柯丁宁; 宋琳琳; 况婷. 实验技术与管理, 2021, 38 (5), 180.
11	Formenti D. ; Ferrett F. ; Scharnagl F. K. ; Beller M. Chem. Rev. 2019, 119, 2611. doi: 10.1021/acs.chemrev.8b00547
12	刘小慧; 苏紫珊; 谢炜桃; 梁家亮; 王小婷; 刘盛杰; 邱燕璇; 柳晓俊; 许伟钦. 化学教育, 2020, 41 (4), 69.
13	周奇; 吴宇恩. 科学通报, 2018, 63 (22), 2246.
14	Hu L. ; Huang Y. M. ; Zhang F. P. ; Chen Q. W. Nanoscale 2013, 5, 4186. doi: 10.1039/c3nr00623a
15	Sasmal A. K. ; Dutta S. ; Pal T. Dalton Trans. 2016, 45, 3139.
16	傅献彩; 沈文霞. 物理化学, 北京: 高等教育出版社, 2006.
17	许伟钦; 邱燕璇; 江涛; 柳晓俊; 关高明; 钱扬义. 实验技术与管理, 2018, 35 (1), 32.

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Preparation and Characterization of Cu Nanoparticles on Porous Carbon: A Recommended Comprehensive Chemistry Experiment

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