分析化学综合实验：分光光度法测定工业油品加氢脱硫催化剂中镍和钼的含量

doi:10.3866/PKU.DXHX202206091

Abstract

Abstract:

Aiming at addressing the problems of single-content and obsolete projects in university-level analytical chemistry, introducing innovative and comprehensive experimental projects into teaching classrooms can enhance students' ability to explore and solve problems independently. Therefore, we designed an experimental teaching scheme that includes sample preparation, characterization and evaluation, as well as data processing and result comparison. The purpose of the experiment is to determine the contents of Ni and Mo in industrial oil hydrodesulfurization catalysts (in this case, Ni-Mo/γ-Al₂O₃ catalysts) using spectrophotometry. The goals are to enable students to understand the fundamentals of conventional supported catalyst preparation and master the quantitative analysis procedure of spectrophotometry.

Key words: Analytical chemistry experiment, Spectrophotometry, Hydrodesulfurization catalysts, Metal content of Ni and Mo, Quantitative analysis

Wenpeng Han, Shujuan Wang, Junping Hu, Ningning Yuan, Chaoqun Li. Determining Nickel and Molybdenum Contents in Industrial Oil Hydrodesulfurization Catalysts Using Spectrophotometry: A Comprehensive Analytical Chemistry Experiment[J].University Chemistry, 2023, 38(5): 149-156.

Figures/Tables 8

References 14

1	胡敏. 炼油技术与工程, 2020, 50 (8), 55.
2	杨闯闯; 杨清河; 孙谦. 工业催化, 2021, 29 (8), 6.
3	刘丽; 郭蓉; 孙进; 丁莉; 杨成敏; 段为宇; 姚运海. 化工进展, 2016, 35 (11), 8.
4	李清清; 严睿; 宋瑞; 彭亚峰. 食品工业, 2021, (9), 308.
5	袁翠宏; 王枝梅; 杨永明; 王梅; 王虹; 陈艳宏; 张庆明. 化学分析计量, 2022, 31 (3), 4.
6	王鑫; 王方平. 广州化工, 2021, 49 (17), 3.
7	褚宁; 蒋晓光; 李卫刚; 王艳君. 岩矿测试,, 2012, 31 (3), 5.
8	象阳; 屈中伟; 赵定义; 李欣; 饶欢. 广东化工, 2013, 40 (24), 43.
9	Ge H. ; Wen X. D. ; Ramos M. A. ; Chianelli R. R. ; Wang S. ; Wane J. ; Qin Z. ; Lyu Z. ; Li X. ACS Catal. 2014, 4 (8), 2556.
10	赵文怡; 许延辉; 孟志军; 刘海娇; 张旭霞. 稀土, 2013, (3), 5.
11	GB/T 4325.9–2013. 钼化学分析方法第9部分: 镍量的测定丁二酮肟分光光度法和火焰原子吸收光谱法.
12	刘标; 卢超培; 覃永振. 材料研究与应用, 2021, 15 (1), 5.
13	蒋克旭; 邓桂春; 姚林; 邢楠楠; 翟玉春. 稀有金属与硬质合金, 2010, 38 (4), 4.
14	王頔; 张建梅; 汪君; 赵建新. 岩矿测试, 2010, (1), 3.

镍标准曲线工作液浓度c/(g∙L⁻¹)	0.05	0.1	0.15	0.2	0.25
相对吸光度A	0.033	0.049	0.064	0.079	0.094

镍标准曲线工作液浓度c/(g∙L⁻¹)	0.1	0.2	0.3	0.4	0.5
相对吸光度A	0.146	0.264	0.390	0.514	0.629

实验测定次数	相对吸光度A (Ni)	相对吸光度A (Mo)
1	0.035	0.131
2	0.035	0.131
3	0.034	0.130

金属含量测定方法	Ni/% (w)	Mo/% (w)
ICP-AES法	5.71	8.89
分光光度法	5.53	8.82

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Determining Nickel and Molybdenum Contents in Industrial Oil Hydrodesulfurization Catalysts Using Spectrophotometry: A Comprehensive Analytical Chemistry Experiment

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