关于《高分子化学》教材中聚酯化反应速率方程推导的探讨

doi:10.3866/PKU.DXHX202209045

Abstract

Abstract:

Owing to the two different types of understanding on the kinetics of irreversible linear polycondensation, various deduction processes of reaction rate expressions exist in different "Polymer Chemistry" textbooks. In this paper, we elaborate the cause of the diversity in the reaction rate expressions derivation via analysis and comparison of a Chinese textbook and an English textbook, "Polymer Chemistry" written by Zuren Pan and "Principles of Polymerization" written by George Odian, respectively. We hope to provide a reference for teachers' teaching and students' learning.

Key words: Polycondensation, Rate expression derivation, Polymer chemistry, Textbook comparison

Mingxiao Deng, Changli Lü, Haizhu Sun. Discussion on Deriving the Rate Expressions of Polyesterification from Different "Polymer Chemistry" Textbooks[J].University Chemistry, 2023, 38(5): 281-284.

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2	Odian, G. Principles of Polymerization, 4th ed.; John Wiley & Sons, Inc., Hoboken, NJ, USA, 2004.
3	Odian, G. Principles of Polymerization. 龙军, 徐慧芳, 陈向群, 黄玉东, 译. 聚合反应原理. 北京: 机械工业出版社, 2013.
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6	潘才元. 高分子化学, 合肥: 中国科学技术大学出版社, 1997.

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Discussion on Deriving the Rate Expressions of Polyesterification from Different "Polymer Chemistry" Textbooks

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