氖的特殊化学物种：研究进展与成键机制

doi:10.12461/PKU.DXHX202508055

Abstract

Abstract: Neon, characterized by its closed-shell 2s²2p⁶ valence electron configuration, is a light noble gas and exhibits pronounced chemical inertness under standard conditions. With the advances in modern chemical methodologies, sophisticated techniques for interrogating potential energy surfaces and in situ experiments under extreme conditions have begun to reveal its latent reactivity. Cryogenic matrix isolation, high-pressure diamond anvil cell experiments and synchrotron radiation-based spectroscopy have uncovered weak interactions between neon and various hosts, achieving the characterization of non-classical compounds. A survey of the literature allows these findings to be classified into three primary categories: inclusion complexes (containing embedded fullerene compounds), ionic compounds with alkali or alkaline earth metals stabilized by high pressure, and van der Waals complexes (including charge-transfer species with carbon tetrachloride) formed with silicon-containing radicals in cryogenic matrices. The bonding mechanisms are highly similar to those of helium compounds that have been reported.

Key words: Noble gas, Neon, Clathrate, Compound, Complex

Jianlin Ren, Bing Li, Yan Guo, Xiangyu Liu. Special chemical species of neon: research progress and bonding mechanism[J].University Chemistry, 2026, 41(9): 182-201.

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Special chemical species of neon: research progress and bonding mechanism

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