3,3-二苯基-3H-萘并吡喃化合物的合成与光致变色性质——一个综合有机化学实验设计与教学实践

doi:10.3866/PKU.DXHX202402050

Abstract

Abstract: A comprehensive organic experiment, focusing on the synthesis and photochromic properties of 3,3-diphenyl-3H-benzo[f]chromene (3H-NP), was developed by incorporating Claisen rearrangement, photochemical reactions, and solid-phase synthesis. The product was synthesized using both liquid-phase and solid-phase methods, and the impact of different synthetic approaches on yield was compared. The photochromic properties of the product were investigated using UV-Vis absorption spectroscopy. By integrating the scientific research process into teaching practice, this experiment aims to foster scientific literacy and innovation skills among undergraduate students.

Key words: 3,3-Diphenyl-3H-Naphthopyran, Solid-phase synthesis, Photochromism, Claisen rearrangement, Green chemistry

Yihao Zhao, Jitian Rao, Jie Han. Synthesis and Photochromic Properties of 3,3-Diphenyl-3H-Naphthopyran: Design and Teaching Practice of a Comprehensive Organic Experiment[J].University Chemistry, 2024, 39(10): 149-155.

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Synthesis and Photochromic Properties of 3,3-Diphenyl-3H-Naphthopyran: Design and Teaching Practice of a Comprehensive Organic Experiment

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