Abstract: The Chemistry “101 Plan” physical chemistry textbook aims to establish a theoretical framework for supernumerary molecular systems. It explores how to link the intelligence and knowledge of individual atoms and molecules with macroscopic supernumerary molecular systems, constructing a chemist’s view of matter and providing scientific thinking methods for studying these systems. The textbook is divided into three parts: the first part covers theoretical foundations, the second part addresses material concepts, and the third part discusses evolutionary laws. This article briefly introduces the theoretical framework of the textbook, aiming to inspire the development of physical chemistry curricula in China and cultivate the next generation of chemistry professionals.

Key words: Chemistry “101 Plan”, Physical chemistry, Textbook